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What is crystảl field 'splitting energy?...

What is crystảl field 'splitting energy? How does the magnitude of 'Delta', decide the actuál configuration of d orbitals in a coordination entity?

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The crystal ficld splitting energy is the energy difference whích results as a splitting of the degenerate d atomic orbitals due tọ the presence of ligands in a definite geometry. It is denoted by .Delta_0. in octahedral field. Figure The magnitude of .Delta_0. decides the actual configuration with how many unpaired electrons present. It means to predict whether the complex in a low spin on high spin complex. Cońsider d..case. .Case 1: If .Delta_0ltp., then the configuration is .t_28^3 eg^prime. There are 4 unpaired electrons present and the. eomplex is a high.spin complex. .e_8 T. .t_2=F. Case 2: If .Delta_0gtp.. then the configuration is .t_2 varepsilon^1 e^0., there aré two unpaired électrons present and the complex is called low spin complex. -e .i.
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V PUBLICATION-COORDINATION COMPOUNDS-QUESTION BANK
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  3. What is crystảl field 'splitting energy? How does the magnitude of 'De...

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  7. Discuss the nature of bonding in metal carbonyIs.

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  8. Give the oxidation state, d-orbital occupation and coordination number...

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  9. Write down the IUPAC name for each of the following complexes and indi...

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  10. What is meant by stability of a coordination compound in solution? Sta...

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