Home
Class 12
CHEMISTRY
The chemistry of the actinoid elements i...

The chemistry of the actinoid elements is not so smooth as that of theb lanthanoids. Justify this statement by giving some examples from the oxidation state of these elements.

Text Solution

Verified by Experts

Lanthanoids show limited number if oxidation state ,`viz,+2,+3` and `+4`(out of which+3 is most common). This is because of large energy gap between `4f,5d` and `6s` subshells, the dominant state of actinoids is also +3 but they show a number of other oxidation states also ,e.g. uranium `(Z=92)` and plutonium `(Z=94)`, show+3+4+5 and +6 neptunium `(Z=94)` show +3+4+5 and +7 etc. this is due to small energy difference between 5f 6d and 7s subshell of the actinoids
Promotional Banner

Topper's Solved these Questions

  • D BLOCK ELEMENTS

    RESONANCE ENGLISH|Exercise MISCELLANEOUS SOLVED PROBLEM (MSPs)|14 Videos
  • D BLOCK ELEMENTS

    RESONANCE ENGLISH|Exercise BOARD LEVEL EXERCISE|21 Videos
  • D & F BLOCK ELEMENTS

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(Aldehydes , Ketones, Carboxylic acid)|15 Videos
  • DPP

    RESONANCE ENGLISH|Exercise QUESTIONS|368 Videos
RESONANCE ENGLISH-D BLOCK ELEMENTS-EXERCISE-3 PART-III
  1. The chemistry of the actinoid elements is not so smooth as that of the...

    Text Solution

    |

  2. Of the ions Ag^(+),Co^(2+) and Ti^(4+) ,which ones will be coloured in...

    Text Solution

    |

  3. Name one ore each of manganese and chromium.

    Text Solution

    |

  4. In the transition series, with an increase in atomic number, the atomi...

    Text Solution

    |

  5. Why Zr and Hf or Nb and Ta exhibit similar properties? Or Zirconium ...

    Text Solution

    |

  6. Why among the lanthanides Ce,(III), can be easily oxidised to Ce(IV) (...

    Text Solution

    |

  7. Explain why E^(@) for Mn^(3+)//Mn^(2+) couple is more positive than th...

    Text Solution

    |

  8. What is the effect of increasing pH on K2Cr2O7 solution?

    Text Solution

    |

  9. What is the basic difference between the electronic configurations of ...

    Text Solution

    |

  10. Why do transition elements shows variable oxidation states?

    Text Solution

    |

  11. Give reasons for each of the following: (i) Size of trivalent lantha...

    Text Solution

    |

  12. The E^(@) value in respect of the electrodes chromium (Z=24), manganes...

    Text Solution

    |

  13. The outer electronic configuration of two members of the lanthanoid se...

    Text Solution

    |

  14. Assign reason for each of the following statement: (i) The largest n...

    Text Solution

    |

  15. Write all possible oxidation states of an element having atomic number...

    Text Solution

    |

  16. Why is +2 oxidation state of manganese quite stable while the same is ...

    Text Solution

    |

  17. How is the variability in oxidation states of transition metals differ...

    Text Solution

    |

  18. Write the electronic configuration of the element with atomic number 1...

    Text Solution

    |

  19. (a) Describe the general trends in the following properties of the fir...

    Text Solution

    |

  20. How would you account for the fact that the transition metals and thei...

    Text Solution

    |

  21. Assign reasons for the following : (i) The enthalpies of atomisatio...

    Text Solution

    |