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Descibe the oxidising actions of potassi...

Descibe the oxidising actions of potassium dichromate and write the ionic equations for its reaction with (i) iodide (ii) iron II solution (iii)`H_(2)S`

A

iodide

B

iron solution

C

`H_(2)S`

D

`H_(2)S`

Text Solution

Verified by Experts

The correct Answer is:
`({:(Cr_(2)O_(7)^(2-)+14H^(+)+6e^(-)to2Cr^(3+)+7H_(2)O),(2I_(2)toI_(2)+2e^(-)xx[3]):})/(Cr_(2)O_(7)^(2-),+14H^(+)+6I^(-),to, 2Cr^(3+)+3I_(2)+7H_(2)O)` (ii) Ferrous salts are oxidised to ferric salts:
`6Fe^(2+)+Cr_(2)O_(7)^(2-)+14H^(+) to 6Fe^(3+)+2Cr^(3+)+7H_(2)O`
(iii) `H_(2)S "is oxidised to sulphur"`:
`Cr_(2)O_(7)^(2-)+3H_(2)S+8H^(+)to2Cr^(3+)+7H_(2)O+3S`
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