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When acidified solution of K(2)Cr(2)O(7)...

When acidified solution of `K_(2)Cr_(2)O_(7)` is shaken with aqeous solution of `FeSO_(4)`, Then:

A

`Cr_(2)O_(7)^(2-) ` ions is reduced to `Cr^(3+)` ions

B

`Cr_(2)O_(7)^(2-)` ion is converted to `CrO_(4)^(2-)` ion

C

`Cr_(2)O_(7)^(2-)` ions is reduced to `Cr`

D

`Cr_(2)O_(7)^(2-)` ions is converted to `CrO_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction between acidified potassium dichromate (K₂Cr₂O₇) and ferrous sulfate (FeSO₄), we can follow these steps: ### Step 1: Identify the Reactants The reactants in this reaction are: - Acidified potassium dichromate (K₂Cr₂O₇) - Aqueous ferrous sulfate (FeSO₄) ### Step 2: Understand the Oxidation States In potassium dichromate (K₂Cr₂O₇), chromium (Cr) is in the +6 oxidation state. In ferrous sulfate (FeSO₄), iron (Fe) is in the +2 oxidation state. ### Step 3: Write the Reaction When K₂Cr₂O₇ is mixed with FeSO₄ in an acidic medium, the reaction can be represented as: \[ K_2Cr_2O_7 + FeSO_4 + H_2SO_4 \rightarrow K_2SO_4 + Fe_2(SO_4)_3 + Cr_2(SO_4)_3 + H_2O \] ### Step 4: Identify the Changes in Oxidation States - Chromium (Cr) in K₂Cr₂O₇ is reduced from +6 to +3. - Iron (Fe) in FeSO₄ is oxidized from +2 to +3. ### Step 5: Determine the Products The chromium from K₂Cr₂O₇ is reduced to Cr³⁺ ions. Therefore, the main product of the reduction of Cr in this reaction is Cr³⁺. ### Conclusion When acidified K₂Cr₂O₇ is shaken with aqueous FeSO₄, the chromium in K₂Cr₂O₇ is reduced to Cr³⁺ ions. ### Final Answer Cr₂O₇²⁻ is reduced to Cr³⁺ ions. ---
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