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In context with the transition elements,...

In context with the transition elements, which of the following statements is incorrect?

A

In the highest oxidation states, the transition metal show basic character and form cationic complexes.

B

In the highest oxidation states. Of the first five transition element. (Sc to Mn), all the `4s` and `3d` electrons are used for bonding

C

Once the `5d` configuration is exceeded, the tendency to involve all the `3d` electrons in bonding decrease.

D

In addition to the normal oxidation state, the zero oxidation state is also shown by these elements in complexes.

Text Solution

Verified by Experts

The correct Answer is:
1

The basic character of any element changes with the oxidation state,low oxidation state are more basic and high oxidation state are more acidic. For example,`MnO` and `Mn_(2)O_(3)` are basic while `Mn_(2)O_(7)` is acidic in nature.
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RESONANCE ENGLISH-D BLOCK ELEMENTS-EXERCISE-3 PART-II
  1. Which of the following group of transition metals is called coinage me...

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  2. The number of d-electrons retained in Fe^(2+) (At. No Fe=26) ions are:

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  3. Ammonia form the complex ion[Cu(NH(3))(4)]^(2+) with copper ions in th...

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  4. The radius of La^(3+)(Z=57) is 106 pm. Which one of the following give...

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  5. Cerium (Z = 58) is an important member of the lanthanoids. Which of th...

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  6. The lanthanide contraction is responsible for the fact that (a)Zr and...

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  7. Which of th following factor may be regarded as the main cause of Lant...

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  8. The spin-only magnetic moment [in units of Bohr magneton, (mu(B) of Ni...

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  9. Lanthanoid contraction is caused due to:

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  10. Identify the incorrect statement among the following.

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  11. The actinoids exhibit more number of oxidation states in general than ...

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  12. More number of oxidation states are exhibited by the actinides than th...

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  13. In context with the transition elements, which of the following statem...

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  14. Knowing that the chemistry of lanthanoids (Ln) is dominated by its +3 ...

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  15. The correct order of E(M^(2+)//M)^@ value with negative sign for the f...

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  16. In context of the lanthanoids , which of the following statement is no...

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  17. The outer electrons configuration of Lu (Atomic No.,71) is :

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  18. Iron exhibits +2 and +3 oxidation states. Which of the following state...

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  19. Which of the following arrangements does not represent the correct ord...

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  20. Four successive members of first row transition element are listed bel...

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