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Why among the lanthanides Ce,(III), can ...

Why among the lanthanides `Ce`,(III), can be easily oxidised to `Ce(IV)` (At. No. of Ce=58). Explain why?
Or of the lanthanides,cerium (At.Nos.58) forms a tetrapositive ion `Ce^(4+)` in aqueous solution. Why?

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The correct Answer is:
`Ce(II)` having the configuration `4f^(1)5d^(@)6s^(@)` can easily lose an electron to acquire the configuration `4f^(@)` and from Ce(IV). In fact , this is the only`(+IV)` lanthanide which exists in solution.
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RESONANCE ENGLISH-D BLOCK ELEMENTS-EXERCISE-3 PART-III
  1. In the transition series, with an increase in atomic number, the atomi...

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  2. Why Zr and Hf or Nb and Ta exhibit similar properties? Or Zirconium ...

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  3. Why among the lanthanides Ce,(III), can be easily oxidised to Ce(IV) (...

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  4. Explain why E^(@) for Mn^(3+)//Mn^(2+) couple is more positive than th...

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  5. What is the effect of increasing pH on K2Cr2O7 solution?

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  6. What is the basic difference between the electronic configurations of ...

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  7. Why do transition elements shows variable oxidation states?

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  8. Give reasons for each of the following: (i) Size of trivalent lantha...

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  9. The E^(@) value in respect of the electrodes chromium (Z=24), manganes...

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  10. The outer electronic configuration of two members of the lanthanoid se...

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  11. Assign reason for each of the following statement: (i) The largest n...

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  12. Write all possible oxidation states of an element having atomic number...

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  13. Why is +2 oxidation state of manganese quite stable while the same is ...

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  14. How is the variability in oxidation states of transition metals differ...

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  15. Write the electronic configuration of the element with atomic number 1...

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  16. (a) Describe the general trends in the following properties of the fir...

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  17. How would you account for the fact that the transition metals and thei...

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  18. Assign reasons for the following : (i) The enthalpies of atomisatio...

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  19. How would you account for the fact that actinoids exhibit a larger num...

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  20. The weak acid, HA has a Ka of 1×10^(−9) . If 0.1 mol of this acid is ...

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