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The outer electronic configuration of tw...

The outer electronic configuration of two members of the lanthanoid series are as follows:
`4f^(1)5d^(1)6s^(2)` and `4f^(7) 5d^(0) 6s^(2)`
What are their atomic number ? Predict the oxidation states exhibited by elements in their compounds.

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The correct Answer is:
To solve the question, we will analyze the given outer electronic configurations of the two lanthanoid elements, determine their atomic numbers, and predict the oxidation states exhibited by these elements in their compounds. ### Step-by-Step Solution: 1. **Identify the first electronic configuration: `4f^(1) 5d^(1) 6s^(2)`** - The outer electronic configuration indicates that there is 1 electron in the 4f subshell, 1 electron in the 5d subshell, and 2 electrons in the 6s subshell. - The element with this configuration is **Cerium (Ce)**. 2. **Determine the atomic number of Cerium:** - The atomic number of Cerium is **58**. This can be confirmed by checking the periodic table. 3. **Predict the oxidation states of Cerium:** - Cerium typically exhibits oxidation states of **+3** and **+4**. - In the +3 oxidation state, Cerium loses three electrons: one from the 4f subshell and two from the 6s subshell, leading to the configuration `4f^(1) 5d^(0) 6s^(0)`. - In the +4 oxidation state, Cerium loses one additional electron from the 5d subshell, leading to the configuration `4f^(0) 5d^(0) 6s^(0)`. 4. **Identify the second electronic configuration: `4f^(7) 5d^(0) 6s^(2)`** - This configuration shows that there are 7 electrons in the 4f subshell, 0 electrons in the 5d subshell, and 2 electrons in the 6s subshell. - The element with this configuration is **Europium (Eu)**. 5. **Determine the atomic number of Europium:** - The atomic number of Europium is **63**. This can also be confirmed by checking the periodic table. 6. **Predict the oxidation states of Europium:** - Europium typically exhibits oxidation states of **+2** and **+3**. - In the +2 oxidation state, Europium loses two electrons from the 6s subshell, leading to the configuration `4f^(7) 5d^(0) 6s^(0)`. - In the +3 oxidation state, Europium loses one additional electron from the 4f subshell, leading to the configuration `4f^(6) 5d^(0) 6s^(0)`. ### Summary of Results: - **Cerium (Ce)**: Atomic number = 58, Oxidation states = +3, +4 - **Europium (Eu)**: Atomic number = 63, Oxidation states = +2, +3
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RESONANCE ENGLISH-D BLOCK ELEMENTS-EXERCISE-3 PART-III
  1. Give reasons for each of the following: (i) Size of trivalent lantha...

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  2. The E^(@) value in respect of the electrodes chromium (Z=24), manganes...

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  3. The outer electronic configuration of two members of the lanthanoid se...

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  4. Assign reason for each of the following statement: (i) The largest n...

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  5. Write all possible oxidation states of an element having atomic number...

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  6. Why is +2 oxidation state of manganese quite stable while the same is ...

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  7. How is the variability in oxidation states of transition metals differ...

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  8. Write the electronic configuration of the element with atomic number 1...

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  9. (a) Describe the general trends in the following properties of the fir...

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  10. How would you account for the fact that the transition metals and thei...

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  11. Assign reasons for the following : (i) The enthalpies of atomisatio...

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  12. How would you account for the fact that actinoids exhibit a larger num...

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  13. The weak acid, HA has a Ka of 1×10^(−9) . If 0.1 mol of this acid is ...

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  14. Explain the following observations: (i) Generally there is an increa...

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  15. How would you account for the following? (i)The atomic radii of the...

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  16. Explain the following : (i) Low spin octahedral complexes of nicke...

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  17. (a) Complete the following chemical equations: (i) Cr(2) O(7)^(2-)...

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  18. How would you account for the following? (i)The atomic radii of the...

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  19. Explain the following observation : (i) Transition elements general...

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  20. What is meant by the 'lanthanide contraction'? Mention one important f...

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