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Which of the following compound is possi...

Which of the following compound is possible :

A

`PbI_(4)`

B

`AlO_(2)`

C

`NaF_(2)`

D

`PbO_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given compounds is possible, we will analyze each option by calculating the oxidation states of the elements involved. ### Step-by-Step Solution: 1. **Option A: PbI4** - Let the oxidation state of Pb be \( x \). - The oxidation state of iodine (I) is \(-1\). - The equation for the compound is: \[ x + 4(-1) = 0 \] - Simplifying gives: \[ x - 4 = 0 \implies x = +4 \] - Lead (Pb) in the +4 oxidation state can act as an oxidizing agent. However, I- is a weak reducing agent and cannot reduce Pb from +4 to 0. Therefore, PbI4 is not stable and the compound is not possible. 2. **Option B: AlO2** - Let the oxidation state of Al be \( x \). - The oxidation state of oxygen (O) is \(-2\). - The equation for the compound is: \[ x + 2(-2) = 0 \] - Simplifying gives: \[ x - 4 = 0 \implies x = +4 \] - The maximum oxidation state of aluminum (Al) is +3. Therefore, AlO2 is not possible. 3. **Option C: NaF2** - Let the oxidation state of Na be \( x \). - The oxidation state of fluorine (F) is \(-1\). - The equation for the compound is: \[ x + 2(-1) = 0 \] - Simplifying gives: \[ x - 2 = 0 \implies x = +2 \] - Sodium (Na) typically has an oxidation state of +1. Therefore, NaF2 is not possible. 4. **Option D: PbO2** - Let the oxidation state of Pb be \( x \). - The oxidation state of oxygen (O) is \(-2\). - The equation for the compound is: \[ x + 2(-2) = 0 \] - Simplifying gives: \[ x - 4 = 0 \implies x = +4 \] - Lead (Pb) can exist in the +4 oxidation state, making PbO2 (lead dioxide) a valid compound. This compound is known to be used in batteries as an electrode. ### Conclusion: The only possible compound among the options given is **PbO2**.
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