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Compare the relative stability of the fo...

Compare the relative stability of the following species and indicate their magnetic properties :
`O_(2) , O_(2)^(+) ,O_(2)^(-) ` ( susperoxide ) `,O_(2)^(2-)` (peroxide )

A

`O_(2)^(2-)gt O_(2)^(-)gt O_(2)gt O_(2)^(+)`

B

`O_(2)^(+)gtO_(2)gtO_(2)^(-)gtO_(2)^(-2)`

C

`O_(2)^(+)gtO_(2)^(-)O_(2)^(-2)gtO_(2)`

D

`O_(2)^(2-)gtO_(2)gtO_(2)^(-)gtO_(2)^(+)`

Text Solution

Verified by Experts

The correct Answer is:
B

Compare the relative ………
Stability `prop` Bond
`O_(2)` - Bond order `= 2`, Paramagnetic
`O_(2)^(+)` - Bond order `= 2.5` , Paramagnetic
`O_(2)^(-)` - Bond order `= 1.5` , Paramagnetic
Order of relative stability is
`O_(2)^(+)gtO_(2)gtO_(2)^(-1)gtO_(2)^(-2)`
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