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for a reversible reaction K(c )gtK(p) at...

for a reversible reaction `K_(c )gtK_(p) at 298 K` and
`Delta H = + 200 KJ` the forward reaction is not favoured by :

A

Increase in pressure

B

Increase in temperature

C

Decrease in pressure

D

Increase in concentration of reactants

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the given conditions for the reversible reaction and determine under which circumstances the forward reaction is not favored. ### Step-by-step Solution: 1. **Understand the Relationship Between Kc and Kp**: The relationship between the equilibrium constants Kc and Kp is given by the equation: \[ K_p = K_c (RT)^{\Delta n} \] where \( \Delta n \) is the change in the number of moles of gas (moles of products - moles of reactants). 2. **Analyze the Given Information**: We know from the question: - \( K_c > K_p \) at 298 K - \( \Delta H = +200 \, \text{kJ} \) (indicating that the reaction is endothermic) 3. **Determine the Sign of \( \Delta n \)**: Since \( K_c > K_p \), it implies that \( \Delta n \) must be negative. This means that the number of moles of products is less than the number of moles of reactants: \[ \Delta n < 0 \quad \Rightarrow \quad n_P < n_R \] 4. **Apply Le Chatelier's Principle**: According to Le Chatelier's Principle, if we increase the pressure of a system, the equilibrium will shift towards the side with fewer moles of gas. Since we have established that \( n_R > n_P \), an increase in pressure will favor the forward reaction. 5. **Consider Temperature Effects**: For endothermic reactions (which absorb heat), increasing the temperature will favor the forward reaction. Conversely, lowering the temperature will favor the reverse reaction. 6. **Conclusion**: Given that the forward reaction is favored by an increase in pressure and an increase in temperature, the condition under which the forward reaction is **not favored** is a **decrease in temperature**. ### Final Answer: The forward reaction is not favored by a decrease in temperature.

To solve the question, we need to analyze the given conditions for the reversible reaction and determine under which circumstances the forward reaction is not favored. ### Step-by-step Solution: 1. **Understand the Relationship Between Kc and Kp**: The relationship between the equilibrium constants Kc and Kp is given by the equation: \[ K_p = K_c (RT)^{\Delta n} ...
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