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Consider one He^+ ion in excited state (...

Consider one `He^+` ion in excited state `(n = 5)`. Which of the following of the following observations will hold true as per the Bohr's model.

A

`10` emission spectral lines will be seen.

B

The ionization energy needed is less than `2 eV`.

C

The longest emitted wavelength is less than `10//R` (`R =` Rydberg's constant).

D

The electronic separtion from the centre of nucleus is more than `6 Å`.

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To solve the problem regarding the `He^+` ion in an excited state (n = 5) and to determine which observations hold true according to Bohr's model, we will analyze each option step by step. ### Step 1: Calculate the number of emission spectral lines According to the formula for the number of spectral lines emitted from an excited state: \[ \text{Number of spectral lines} = \frac{n(n-1)}{2} \] For `n = 5`: \[ \text{Number of spectral lines} = \frac{5(5-1)}{2} = \frac{5 \times 4}{2} = 10 \] **Conclusion**: Option A is correct. ### Step 2: Calculate the ionization energy The ionization energy can be calculated using the formula: \[ E_n = -\frac{13.6 \, \text{eV} \times Z^2}{n^2} \] For `He^+`, \( Z = 2 \) and \( n = 5 \): \[ E_5 = -\frac{13.6 \times 2^2}{5^2} = -\frac{13.6 \times 4}{25} = -2.176 \, \text{eV} \] The ionization energy (enthalpy) is the energy required to remove the electron from the ion: \[ \text{Ionization Energy} = 0 - E_5 = 0 - (-2.176) = 2.176 \, \text{eV} \] **Conclusion**: The ionization energy is greater than 2 eV, so Option B is incorrect. ### Step 3: Calculate the longest emitted wavelength Using the Rydberg formula: \[ \frac{1}{\lambda} = RZ^2 \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] For the longest wavelength, we take \( n_1 = 4 \) and \( n_2 = 5 \): \[ \frac{1}{\lambda} = R \cdot 2^2 \left( \frac{1}{4^2} - \frac{1}{5^2} \right) = 4R \left( \frac{1}{16} - \frac{1}{25} \right) \] Calculating the fractions: \[ \frac{1}{16} - \frac{1}{25} = \frac{25 - 16}{400} = \frac{9}{400} \] Thus: \[ \frac{1}{\lambda} = 4R \cdot \frac{9}{400} = \frac{36R}{400} = \frac{9R}{100} \] So, the wavelength \( \lambda \) is: \[ \lambda = \frac{100}{9R} \] Since \( \frac{100}{9R} \) is greater than \( \frac{10}{R} \), Option C is incorrect. ### Step 4: Calculate the electronic separation from the nucleus The radius of the orbit can be calculated using: \[ R_n = 0.53 \frac{n^2}{Z} \, \text{Å} \] For `n = 5` and `Z = 2`: \[ R_5 = 0.53 \frac{5^2}{2} = 0.53 \frac{25}{2} = 0.53 \times 12.5 = 6.625 \, \text{Å} \] **Conclusion**: The electronic separation from the center of the nucleus is greater than 6 Å, so Option D is correct. ### Final Summary - Option A: Correct (10 emission spectral lines) - Option B: Incorrect (Ionization energy is greater than 2 eV) - Option C: Incorrect (Longest emitted wavelength is greater than \( \frac{10}{R} \)) - Option D: Correct (Electronic separation is more than 6 Å)

To solve the problem regarding the `He^+` ion in an excited state (n = 5) and to determine which observations hold true according to Bohr's model, we will analyze each option step by step. ### Step 1: Calculate the number of emission spectral lines According to the formula for the number of spectral lines emitted from an excited state: \[ \text{Number of spectral lines} = \frac{n(n-1)}{2} \] For `n = 5`: ...
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