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1 mol of a real gas obeys P(V(m) - b) = ...

`1` mol of a real gas obeys `P(V_(m) - b) = RT` , where `'b'` and `'R'` are constants. If the compressibility factor of gas is `1. 11` and occupied volume of the gas is `Xb` then determine value of `X//2`.

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To solve the problem, we start with the given equation for the real gas: 1. **Given Equation**: \[ P(V_m - b) = RT \] where \( b \) and \( R \) are constants. 2. **Compressibility Factor**: The compressibility factor \( Z \) is given as: \[ Z = 1.11 \] The formula for the compressibility factor is: \[ Z = 1 + \frac{Pb}{RT} \] 3. **Substituting the Value of Z**: Substitute \( Z = 1.11 \) into the compressibility factor equation: \[ 1.11 = 1 + \frac{Pb}{RT} \] Rearranging gives: \[ \frac{Pb}{RT} = 1.11 - 1 = 0.11 \] 4. **Rearranging for \( \frac{RT}{P} \)**: From the above equation, we can express \( \frac{RT}{P} \): \[ \frac{RT}{P} = \frac{b}{0.11} \] 5. **Using the Ideal Gas Equation**: From the original equation \( P(V_m - b) = RT \), we can express \( V_m - b \): \[ V_m - b = \frac{RT}{P} \] 6. **Equating the Two Expressions**: Now we have two expressions for \( \frac{RT}{P} \): \[ V_m - b = \frac{b}{0.11} \] Setting them equal gives: \[ V_m - b = \frac{b}{0.11} \] 7. **Solving for \( V_m \)**: Rearranging the equation: \[ V_m = b + \frac{b}{0.11} \] To combine the terms, we can factor out \( b \): \[ V_m = b \left(1 + \frac{1}{0.11}\right) = b \left(1 + 9.09\right) = b \cdot 10.09 \] Thus, we approximate: \[ V_m \approx 10b \] 8. **Relating \( V_m \) to Occupied Volume**: We know from the problem that the occupied volume of the gas is \( Xb \): \[ V_m = Xb \] Setting the two equations equal: \[ 10b = Xb \] 9. **Solving for \( X \)**: Dividing both sides by \( b \) (assuming \( b \neq 0 \)): \[ X = 10 \] 10. **Finding \( \frac{X}{2} \)**: Finally, we need to find \( \frac{X}{2} \): \[ \frac{X}{2} = \frac{10}{2} = 5 \] Thus, the final answer is: \[ \frac{X}{2} = 5 \]

To solve the problem, we start with the given equation for the real gas: 1. **Given Equation**: \[ P(V_m - b) = RT \] where \( b \) and \( R \) are constants. ...
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