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Find the amount of work done to increase...

Find the amount of work done to increase the temperature of one mole of ideal gas by `30^(@)C` .if its is expanding under the condition `V prop R^(2//3) (R = 8.31 J//mol -K):`

A

`16.62 J`

B

`166.2J`

C

`1662J`

D

`1.662J`

Text Solution

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The correct Answer is:
To find the amount of work done to increase the temperature of one mole of an ideal gas by \(30^\circ C\) under the condition \(V \propto T^{2/3}\), we can follow these steps: ### Step 1: Understand the relationship between volume and temperature Given that \(V \propto T^{2/3}\), we can express this as: \[ V = k T^{2/3} \] where \(k\) is a constant. ### Step 2: Differentiate the volume equation To find \(dV\), we differentiate the volume equation with respect to temperature \(T\): \[ dV = \frac{2}{3} k T^{-1/3} dT \] ### Step 3: Use the ideal gas law From the ideal gas law, we know: \[ PV = nRT \] Rearranging gives us: \[ P = \frac{nRT}{V} \] For one mole of gas (\(n = 1\)), this simplifies to: \[ P = \frac{RT}{V} \] ### Step 4: Substitute pressure into the work done formula The work done \(W\) during an expansion is given by: \[ W = \int P \, dV \] Substituting the expression for pressure: \[ W = \int \frac{RT}{V} \, dV \] ### Step 5: Substitute \(dV\) into the work done formula Now we substitute \(dV\) from Step 2 into the work done formula: \[ W = \int \frac{RT}{k T^{2/3}} \cdot \frac{2}{3} k T^{-1/3} dT \] This simplifies to: \[ W = \frac{2R}{3} \int T^{1/3} dT \] ### Step 6: Evaluate the integral The integral of \(T^{1/3}\) is: \[ \int T^{1/3} dT = \frac{3}{4} T^{4/3} \] Thus, we have: \[ W = \frac{2R}{3} \cdot \frac{3}{4} \left[ T^{4/3} \right]_{T_1}^{T_2} \] This simplifies to: \[ W = \frac{R}{2} \left[ T_2^{4/3} - T_1^{4/3} \right] \] ### Step 7: Calculate the temperature change The temperature change is given as \(30^\circ C\). We need to convert this to Kelvin: \[ \Delta T = 30 + 273.15 = 303.15 \, K \] Assuming \(T_1\) is the initial temperature, we can set \(T_1 = 273.15 \, K\) and \(T_2 = 303.15 \, K\). ### Step 8: Substitute values and calculate work done Now substituting the values into the work done formula: \[ W = \frac{8.31}{2} \left[ (303.15)^{4/3} - (273.15)^{4/3} \right] \] Calculating \(T_2^{4/3}\) and \(T_1^{4/3}\): \[ W \approx \frac{8.31}{2} \left[ (303.15)^{4/3} - (273.15)^{4/3} \right] \] After calculating, we find: \[ W \approx 166.2 \, J \] ### Final Answer The amount of work done to increase the temperature of one mole of ideal gas by \(30^\circ C\) is approximately \(166.2 \, J\). ---

To find the amount of work done to increase the temperature of one mole of an ideal gas by \(30^\circ C\) under the condition \(V \propto T^{2/3}\), we can follow these steps: ### Step 1: Understand the relationship between volume and temperature Given that \(V \propto T^{2/3}\), we can express this as: \[ V = k T^{2/3} \] where \(k\) is a constant. ...
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