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4 moles of H(2) at 500K is mixed with 2 ...

`4` moles of `H_(2) at 500K` is mixed with `2` moles of `He` at `400k`. The mixture attains a temperature `T` and volume `V`. Now the mixture is compressed adiabatically to a volume `V'` and temperature `T'`. If `(T')/(T) = ((V)/(V'))^(n)`, find the value of `13n`.

A

`4`

B

`6`

C

`5`

D

`13`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to follow these steps: ### Step 1: Determine the specific heat capacities (Cv) for each gas. - For hydrogen (H₂), which is a diatomic gas, the specific heat capacity at constant volume (Cv) is given by: \[ C_{v,\text{H}_2} = \frac{5R}{2} \] - For helium (He), which is a monatomic gas, the specific heat capacity at constant volume (Cv) is given by: \[ C_{v,\text{He}} = \frac{3R}{2} \] ### Step 2: Calculate the total Cv for the mixture. - The total number of moles in the mixture is: \[ n_{\text{total}} = n_{\text{H}_2} + n_{\text{He}} = 4 + 2 = 6 \] - The total Cv for the mixture can be calculated as: \[ C_{v,\text{mixture}} = \frac{n_{\text{H}_2} \cdot C_{v,\text{H}_2} + n_{\text{He}} \cdot C_{v,\text{He}}}{n_{\text{total}}} \] \[ C_{v,\text{mixture}} = \frac{4 \cdot \frac{5R}{2} + 2 \cdot \frac{3R}{2}}{6} \] \[ = \frac{10R + 3R}{6} = \frac{13R}{6} \] ### Step 3: Find the value of γ for the mixture. - The value of γ (gamma) is related to Cv by: \[ \gamma = \frac{C_p}{C_v} \] - Since \( C_p = C_v + R \), we have: \[ C_{p,\text{mixture}} = C_{v,\text{mixture}} + R = \frac{13R}{6} + R = \frac{13R}{6} + \frac{6R}{6} = \frac{19R}{6} \] - Thus, we can find γ: \[ \gamma_{\text{mixture}} = \frac{C_{p,\text{mixture}}}{C_{v,\text{mixture}}} = \frac{\frac{19R}{6}}{\frac{13R}{6}} = \frac{19}{13} \] ### Step 4: Use the adiabatic relation. - The adiabatic relation is given by: \[ T V^{\gamma - 1} = \text{constant} \] - For initial and final states, we can write: \[ T V^{\gamma - 1} = T' V'^{\gamma - 1} \] - This leads to: \[ \frac{T'}{T} = \left(\frac{V}{V'}\right)^{\gamma - 1} \] - Substituting \( \gamma - 1 = \frac{19}{13} - 1 = \frac{6}{13} \): \[ \frac{T'}{T} = \left(\frac{V}{V'}\right)^{\frac{6}{13}} \] ### Step 5: Compare with the given relation. - The problem states: \[ \frac{T'}{T} = \left(\frac{V}{V'}\right)^{n} \] - By comparing both equations, we find: \[ n = \frac{6}{13} \] ### Step 6: Calculate \( 13n \). - Now, we can find \( 13n \): \[ 13n = 13 \cdot \frac{6}{13} = 6 \] ### Final Answer: Thus, the value of \( 13n \) is \( \boxed{6} \). ---

To solve the problem, we need to follow these steps: ### Step 1: Determine the specific heat capacities (Cv) for each gas. - For hydrogen (H₂), which is a diatomic gas, the specific heat capacity at constant volume (Cv) is given by: \[ C_{v,\text{H}_2} = \frac{5R}{2} \] - For helium (He), which is a monatomic gas, the specific heat capacity at constant volume (Cv) is given by: ...
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