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Comprehension-3 An ideal gas initially...

Comprehension-3
An ideal gas initially at pressure `p_(0)` undergoes a free expansion (expansion against vacuum under adiabatic conditions) until its volume is `3` times its initial volume. The gas is next adiabatically compressed back to its original volume. The pressure after compression is `3^(2//3)p_(0)`.
The pressure of the gas after the free expansion is:

A

`(p_(0))/(3)`

B

`p_(0)^(1//3)`

C

`p_(0)`

D

`3p_(0)`

Text Solution

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The correct Answer is:
To solve the problem, we will analyze the situation step by step. ### Step 1: Understand the Initial Conditions Initially, we have an ideal gas at pressure \( p_0 \) and volume \( V_0 \). The temperature is \( T_0 \). ### Step 2: Free Expansion The gas undergoes a free expansion against a vacuum until its volume becomes three times its initial volume. Therefore, the final volume after the free expansion is: \[ V_B = 3V_0 \] ### Step 3: Analyze the Free Expansion Process In a free expansion: - There is no external pressure opposing the expansion (since it is against a vacuum). - The process is adiabatic, meaning there is no heat exchange with the surroundings (\( Q = 0 \)). - The work done by the gas is also zero (\( W = 0 \)) because there is no opposing force. ### Step 4: Apply the First Law of Thermodynamics According to the first law of thermodynamics: \[ Q = \Delta U + W \] Since \( Q = 0 \) and \( W = 0 \), we have: \[ 0 = \Delta U + 0 \implies \Delta U = 0 \] This indicates that the internal energy of the gas does not change during the free expansion. ### Step 5: Relate Internal Energy to Temperature For an ideal gas, the change in internal energy (\( \Delta U \)) is given by: \[ \Delta U = nC_v \Delta T \] Since \( \Delta U = 0 \), it follows that: \[ \Delta T = 0 \] This means the temperature of the gas remains constant during the free expansion. ### Step 6: Use the Ideal Gas Law Since the temperature remains constant, we can use the ideal gas law: \[ PV = nRT \] At the initial state (point A): \[ p_0 V_0 = nRT_0 \] At the final state after free expansion (point B): \[ P_B \cdot (3V_0) = nRT_0 \] Since \( nRT_0 \) is constant, we can equate the two states: \[ p_0 V_0 = P_B \cdot (3V_0) \] ### Step 7: Solve for \( P_B \) Dividing both sides by \( V_0 \) (assuming \( V_0 \neq 0 \)): \[ p_0 = P_B \cdot 3 \] Rearranging gives: \[ P_B = \frac{p_0}{3} \] ### Conclusion The pressure of the gas after the free expansion is: \[ \boxed{\frac{p_0}{3}} \]
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