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Consider atoms H, He^(+), Li^(++) in the...

Consider atoms `H, He^(+), Li^(++)` in their ground states. If `L_(1), L_(2)` and `L_(3)` are magnitude of angular momentum of their electrons about the nucleus respectively then:

A. `L_(1)=L_(2)=L_(3)`
B. `L_(1) gt L_(2) gt L_(3)`
C. `L_(1) lt L_(2) lt L_(3)`
D. `L_(1)=L_(2)=L_(3)`

A

`L_(1)=L_(2)=L_(3)`

B

`L_(1) gt L_(2) gt L_(3)`

C

`L_(1) lt L_(2) lt L_(3)`

D

`L_(1)=L_(2)=L_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the angular momentum of the electrons in the ground states of the hydrogen atom (H), the singly ionized helium atom (He⁺), and the doubly ionized lithium atom (Li²⁺). ### Step-by-Step Solution: 1. **Identify the Principal Quantum Numbers (n)**: - In the ground state, the principal quantum number \( n \) for hydrogen (H) is 1. - For helium (He⁺), which has one electron in the ground state, \( n \) is also 1. - For lithium (Li²⁺), which has two electrons but only one is in the ground state (the outermost electron), \( n \) is still 1. 2. **Angular Momentum Formula**: - The magnitude of angular momentum \( L \) of an electron in an atom is given by the formula: \[ L = n \frac{h}{2\pi} \] - Here, \( h \) is Planck's constant and \( n \) is the principal quantum number. 3. **Calculate Angular Momentum for Each Atom**: - For hydrogen (H): \[ L_1 = 1 \cdot \frac{h}{2\pi} = \frac{h}{2\pi} \] - For helium (He⁺): \[ L_2 = 1 \cdot \frac{h}{2\pi} = \frac{h}{2\pi} \] - For lithium (Li²⁺): \[ L_3 = 1 \cdot \frac{h}{2\pi} = \frac{h}{2\pi} \] 4. **Compare the Angular Momenta**: - We find that: \[ L_1 = L_2 = L_3 = \frac{h}{2\pi} \] 5. **Conclusion**: - Since the angular momenta of all three atoms are equal, we conclude that: \[ L_1 = L_2 = L_3 \] ### Final Answer: The correct option is **A. \( L_1 = L_2 = L_3 \)**.

To solve the problem, we need to analyze the angular momentum of the electrons in the ground states of the hydrogen atom (H), the singly ionized helium atom (He⁺), and the doubly ionized lithium atom (Li²⁺). ### Step-by-Step Solution: 1. **Identify the Principal Quantum Numbers (n)**: - In the ground state, the principal quantum number \( n \) for hydrogen (H) is 1. - For helium (He⁺), which has one electron in the ground state, \( n \) is also 1. - For lithium (Li²⁺), which has two electrons but only one is in the ground state (the outermost electron), \( n \) is still 1. ...
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