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The ionization energy of a hydrogen like...

The ionization energy of a hydrogen like Bohr atom is `4` Rydberg. If the wavelength of radiation emitted when the electron jumps from the first excited state to the ground state is `N-m` and if the radius of the first orbit of this atom is `r-m` then the value of `(N)/(r )=Pxx10^(2)` then, value of `P`. (Bohr radius of hydrogen `=5xx10^(-11)m,1` Rydberg `=2.2xx10^(-18)J`)

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To solve the problem, we will follow these steps: ### Step 1: Determine the Atomic Number (Z) The ionization energy \( E_{\text{ionization}} \) is given as \( 4 \) Rydbergs. The energy of the nth orbit in a hydrogen-like atom is given by: \[ E_n = -R_H \cdot \frac{Z^2}{n^2} \] where \( R_H \) is the Rydberg constant for hydrogen, which is \( 1 \) Rydberg \( = 2.2 \times 10^{-18} \, J \). For the ground state (n=1): \[ E_1 = -R_H \cdot Z^2 \] For ionization (n approaches infinity): \[ E_{\infty} = 0 \] Thus, the ionization energy can be expressed as: \[ E_{\text{ionization}} = E_{\infty} - E_1 = 0 - (-R_H \cdot Z^2) = R_H \cdot Z^2 \] Setting this equal to \( 4 \) Rydbergs: \[ R_H \cdot Z^2 = 4 \cdot R_H \] Cancelling \( R_H \): \[ Z^2 = 4 \implies Z = 2 \] ### Step 2: Calculate the Wavelength (N) The electron jumps from the first excited state (n=2) to the ground state (n=1). The energy difference between these states is: \[ \Delta E = E_2 - E_1 = -R_H \cdot \frac{Z^2}{2^2} - (-R_H \cdot Z^2) = R_H \cdot Z^2 \left(1 - \frac{1}{4}\right) = R_H \cdot Z^2 \cdot \frac{3}{4} \] Substituting \( Z = 2 \): \[ \Delta E = R_H \cdot 4 \cdot \frac{3}{4} = 3 \cdot R_H \] Using the relation \( E = \frac{hc}{\lambda} \): \[ \lambda = \frac{hc}{\Delta E} \] Substituting \( \Delta E = 3 \cdot R_H \): \[ \lambda = \frac{hc}{3 \cdot R_H} \] Using \( h = 6.63 \times 10^{-34} \, J \cdot s \) and \( c = 3 \times 10^8 \, m/s \): \[ \lambda = \frac{(6.63 \times 10^{-34})(3 \times 10^8)}{3 \cdot (2.2 \times 10^{-18})} \] Calculating: \[ \lambda = \frac{1.989 \times 10^{-25}}{6.6 \times 10^{-18}} \approx 3.01 \times 10^{-8} \, m = 3 \, \text{nm} \] ### Step 3: Calculate the Radius (r) The radius of the first orbit is given by: \[ r_n = \frac{n^2 \cdot R_B}{Z} \] For \( n = 1 \): \[ r_1 = \frac{1^2 \cdot R_B}{Z} = \frac{R_B}{2} \] Given \( R_B = 5 \times 10^{-11} \, m \): \[ r_1 = \frac{5 \times 10^{-11}}{2} = 2.5 \times 10^{-11} \, m \] ### Step 4: Calculate \( \frac{N}{r} \) Now we can find \( \frac{N}{r} \): \[ \frac{N}{r} = \frac{3 \times 10^{-8}}{2.5 \times 10^{-11}} = 1.2 \times 10^3 \] This can be expressed as: \[ \frac{N}{r} = 1.2 \times 10^3 = P \times 10^2 \] Thus, \( P = 12 \). ### Final Answer The value of \( P \) is \( 12 \). ---

To solve the problem, we will follow these steps: ### Step 1: Determine the Atomic Number (Z) The ionization energy \( E_{\text{ionization}} \) is given as \( 4 \) Rydbergs. The energy of the nth orbit in a hydrogen-like atom is given by: \[ E_n = -R_H \cdot \frac{Z^2}{n^2} \] where \( R_H \) is the Rydberg constant for hydrogen, which is \( 1 \) Rydberg \( = 2.2 \times 10^{-18} \, J \). ...
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