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when Z is doubled in an atom, which of t...

when `Z` is doubled in an atom, which of the following statements are consistent with Bohr's theory?

A

Energy of a state is double

B

Radius of an orbit is doubled.

C

Velocity of electrons in an orbit is doubled.

D

Radius of an orbit is halved.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the effects of doubling the atomic number \( Z \) in an atom according to Bohr's theory, we will analyze the relationships between \( Z \), energy, radius, and velocity of the electron in the orbit. ### Step-by-Step Solution: 1. **Understanding the Energy Relation**: According to Bohr's theory, the energy \( E \) of an electron in a hydrogen-like atom is given by the formula: \[ E \propto -Z^2 \] If \( Z \) is doubled (i.e., \( Z' = 2Z \)), then: \[ E' \propto -(2Z)^2 = -4Z^2 \] This indicates that the energy becomes four times more negative (or four times the magnitude) compared to the original energy. Therefore, the energy does not double; it quadruples. **Hint**: Remember that energy is proportional to the square of the atomic number \( Z \). 2. **Understanding the Radius Relation**: The radius \( r \) of the electron's orbit is given by: \[ r \propto \frac{1}{Z} \] If \( Z \) is doubled, then: \[ r' \propto \frac{1}{2Z} = \frac{1}{2}r \] This means the radius becomes half of its original value. **Hint**: The radius is inversely proportional to the atomic number \( Z \). 3. **Understanding the Velocity Relation**: The velocity \( v \) of the electron in the orbit is given by: \[ v \propto Z \] If \( Z \) is doubled, then: \[ v' \propto 2Z \] This indicates that the velocity doubles. **Hint**: Velocity is directly proportional to the atomic number \( Z \). ### Summary of Findings: - Energy does not double; it quadruples. - The radius of the orbit becomes half. - The velocity of the electron doubles. ### Conclusion: From the analysis: - The correct statements consistent with Bohr's theory when \( Z \) is doubled are: - The radius of the orbit is half. - The velocity of the electron is doubled. Thus, the correct options are: - **C**: The radius of an orbit is half. - **D**: The velocity is doubled.
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