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Sucrose on hydrolysis yields a mixture w...

Sucrose on hydrolysis yields a mixture which is.

A

optically inactive

B

dextrorotatory

C

laevorotatory

D

racemic

Text Solution

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The correct Answer is:
To solve the question "Sucrose on hydrolysis yields a mixture which is," we can follow these steps: ### Step 1: Understand the Hydrolysis of Sucrose - Sucrose (C12H22O11) is a disaccharide composed of glucose and fructose. - When sucrose undergoes hydrolysis, it reacts with water (H2O) in the presence of an acid (like HCl) to break down into its constituent monosaccharides. ### Step 2: Write the Hydrolysis Reaction - The reaction can be represented as: \[ \text{C}_{12}\text{H}_{22}\text{O}_{11} + \text{H}_2\text{O} \xrightarrow{\text{HCl}} \text{C}_6\text{H}_{12}\text{O}_6 + \text{C}_6\text{H}_{12}\text{O}_6 \] - This results in the formation of D-glucose and D-fructose. ### Step 3: Analyze the Optical Activity - D-glucose is dextrorotatory (rotates plane-polarized light to the right) with a specific rotation of +52.5°. - D-fructose is levorotatory (rotates plane-polarized light to the left) with a specific rotation of -92.4°. ### Step 4: Determine the Resulting Mixture's Optical Activity - Since the hydrolysis of sucrose produces an equimolar mixture of D-glucose and D-fructose, we need to consider their specific rotations. - The total specific rotation of the mixture can be calculated by considering the contributions from both sugars: - D-glucose contributes +52.5°. - D-fructose contributes -92.4°. ### Step 5: Compare the Contributions - Since the absolute value of the specific rotation of fructose (-92.4°) is greater than that of glucose (+52.5°), the resulting mixture will be levorotatory. - Therefore, the mixture will exhibit a net levorotatory rotation. ### Conclusion - The hydrolysis of sucrose yields a mixture that is levorotatory. ### Final Answer - The correct answer is that sucrose on hydrolysis yields a mixture which is **levorotatory**. ---

To solve the question "Sucrose on hydrolysis yields a mixture which is," we can follow these steps: ### Step 1: Understand the Hydrolysis of Sucrose - Sucrose (C12H22O11) is a disaccharide composed of glucose and fructose. - When sucrose undergoes hydrolysis, it reacts with water (H2O) in the presence of an acid (like HCl) to break down into its constituent monosaccharides. ### Step 2: Write the Hydrolysis Reaction - The reaction can be represented as: ...
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