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The correct statements about anomers are...

The correct statements about anomers are

A

Anomers have different stereochemistry at `C-1` (anomeric carbon)

B

`alpha-D`glucopyranose and `beta-D-`glucopyranose can be crystallised and purified

C

When pure `alpha-D-`glucopyranose is dissolved in water is optical rotation slowly changes

D

When pure `alpha`-D-glucopyranose and one carboxylic acid, group are available for reaction, then only one dipeptide can forms.

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct statements about anomers, we will analyze each statement one by one. ### Step-by-Step Solution: 1. **Understanding Anomers**: Anomers are a type of stereoisomer that differ at the anomeric carbon (C1) in a cyclic sugar. This is crucial to understanding the first statement. 2. **Evaluating Statement A**: - **Statement**: Anomers have different stereochemistry at C1, which is called the anomeric carbon. - **Analysis**: This statement is **correct** because anomers are defined by their difference in configuration at the anomeric carbon. 3. **Evaluating Statement B**: - **Statement**: Alpha-D-glucopyranose and beta-D-glucopyranose can be crystallized and purified. - **Analysis**: This statement is also **correct**. The two forms have different melting points (146°C for alpha-D-glucose and 150°C for beta-D-glucose), allowing for their separation through crystallization. 4. **Evaluating Statement C**: - **Statement**: When pure alpha-D-glucopyranose is dissolved in water, its optical rotation slowly changes. - **Analysis**: This statement is **correct** due to the phenomenon of mutarotation. When alpha-D-glucose is dissolved in water, it can interconvert with beta-D-glucose and the open-chain form, leading to a change in optical rotation over time. 5. **Evaluating Statement D**: - **Statement**: When pure alpha-D-glucopyranose and one carboxylic acid group are available for the reaction, then only one dipeptide can form. - **Analysis**: This statement is **false**. Dipeptides are formed between an amino group and a carboxylic acid group. Since alpha-D-glucopyranose does not contain an amino group, it cannot form a dipeptide. ### Conclusion: The correct statements about anomers are A, B, and C. ### Final Answer: The correct statements about anomers are: - A: Anomers have different stereochemistry at C1. - B: Alpha-D-glucopyranose and beta-D-glucopyranose can be crystallized and purified. - C: When pure alpha-D-glucopyranose is dissolved in water, its optical rotation slowly changes.

To determine the correct statements about anomers, we will analyze each statement one by one. ### Step-by-Step Solution: 1. **Understanding Anomers**: Anomers are a type of stereoisomer that differ at the anomeric carbon (C1) in a cyclic sugar. This is crucial to understanding the first statement. 2. **Evaluating Statement A**: ...
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