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In a two step exothermic reaction A(2)...

In a two step exothermic reaction
`A_(2)(g) + B_(2)(g) hArr 3C(g) hArr D(g)," "DeltaH=-ve` steps `1 & 2` are favoured respectively by .

A

High pressure, high temperature & low pressure, low temperature

B

Low pressure, low temperature & high pressure, low temperature

C

High pressure, low temperature & low pressure, low temperature

D

Low pressure, high temperature & high pressure, high temperature

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem regarding the two-step exothermic reaction: **Step 1: Understand the Reaction** The reaction is given as: 1. \( A_2(g) + B_2(g) \rightleftharpoons 3C(g) \) (Step 1) 2. \( 3C(g) \rightleftharpoons D(g) \) (Step 2) Both steps are exothermic, indicated by \( \Delta H < 0 \). **Step 2: Analyze the Effect of Temperature** For exothermic reactions, according to Le Chatelier's principle, lowering the temperature favors the forward reaction. Therefore, both steps will be favored at low temperatures. **Step 3: Analyze the Effect of Pressure** - **Step 1:** - Initial moles: \( 2 \) (from \( A_2 \) and \( B_2 \)) - Final moles: \( 3 \) (from \( 3C \)) - Since the number of moles increases (from 2 to 3), decreasing the pressure will favor this step. - **Step 2:** - Initial moles: \( 3 \) (from \( 3C \)) - Final moles: \( 1 \) (from \( D \)) - Since the number of moles decreases (from 3 to 1), increasing the pressure will favor this step. **Step 4: Conclusion** - Step 1 is favored by low temperature and low pressure. - Step 2 is favored by low temperature and high pressure. Thus, the correct answer is that both steps are favored at low temperature, with Step 1 favored by low pressure and Step 2 favored by high pressure. **Final Answer:** The conditions that favor steps 1 and 2 respectively are: - Step 1: Low temperature and low pressure - Step 2: Low temperature and high pressure

To solve the problem regarding the two-step exothermic reaction: **Step 1: Understand the Reaction** The reaction is given as: 1. \( A_2(g) + B_2(g) \rightleftharpoons 3C(g) \) (Step 1) 2. \( 3C(g) \rightleftharpoons D(g) \) (Step 2) Both steps are exothermic, indicated by \( \Delta H < 0 \). ...
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