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For A(g) hArr 2B(g), equilibrium constan...

For `A(g) hArr 2B(g)`, equilibrium constant at total equilibrium pressure `p_(1)` is
`K_(p1)& ` for `C(g)hArrD(g)+E(g)`.
equilibrium constant at total equilibrium pressure `p_(2)` is `K_(p2)`. If degree of dissciation of `A & C` are same, then the ratio `K_(p1) //K_(p2)` , if `2p_(1)=p_(2)`, is `:`

A

2

B

`1//8`

C

`1//2`

D

8

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to find the ratio \( \frac{K_{p1}}{K_{p2}} \) given the reactions and conditions provided. Let's break down the solution step by step. ### Step 1: Analyze the first reaction \( A(g) \rightleftharpoons 2B(g) \) 1. **Initial Moles**: Assume at time \( t = 0 \): - Moles of \( A = 1 \) - Moles of \( B = 0 \) 2. **At Equilibrium**: Let the degree of dissociation of \( A \) be \( \alpha \). - Moles of \( A = 1 - \alpha \) - Moles of \( B = 2\alpha \) 3. **Total Moles at Equilibrium**: \[ n_{total} = (1 - \alpha) + 2\alpha = 1 + \alpha \] 4. **Expression for \( K_{p1} \)**: \[ K_{p1} = \frac{(P_B)^2}{P_A} = \frac{(2\alpha \cdot \frac{P_1}{1 + \alpha})^2}{(1 - \alpha) \cdot \frac{P_1}{1 + \alpha}} \] Simplifying this gives: \[ K_{p1} = \frac{4\alpha^2 P_1}{(1 - \alpha)(1 + \alpha)} \] ### Step 2: Analyze the second reaction \( C(g) \rightleftharpoons D(g) + E(g) \) 1. **Initial Moles**: Assume at time \( t = 0 \): - Moles of \( C = 1 \) - Moles of \( D = 0 \) - Moles of \( E = 0 \) 2. **At Equilibrium**: Let the degree of dissociation of \( C \) be \( \alpha \). - Moles of \( C = 1 - \alpha \) - Moles of \( D = \alpha \) - Moles of \( E = \alpha \) 3. **Total Moles at Equilibrium**: \[ n_{total} = (1 - \alpha) + \alpha + \alpha = 1 + \alpha \] 4. **Expression for \( K_{p2} \)**: \[ K_{p2} = \frac{(P_D)(P_E)}{P_C} = \frac{(\alpha \cdot \frac{P_2}{1 + \alpha})(\alpha \cdot \frac{P_2}{1 + \alpha})}{(1 - \alpha) \cdot \frac{P_2}{1 + \alpha}} \] Simplifying this gives: \[ K_{p2} = \frac{\alpha^2 P_2}{(1 - \alpha)(1 + \alpha)} \] ### Step 3: Find the ratio \( \frac{K_{p1}}{K_{p2}} \) 1. **Setting up the ratio**: \[ \frac{K_{p1}}{K_{p2}} = \frac{\frac{4\alpha^2 P_1}{(1 - \alpha)(1 + \alpha)}}{\frac{\alpha^2 P_2}{(1 - \alpha)(1 + \alpha)}} \] The terms \( (1 - \alpha)(1 + \alpha) \) cancel out: \[ \frac{K_{p1}}{K_{p2}} = \frac{4P_1}{P_2} \] 2. **Using the condition \( 2P_1 = P_2 \)**: \[ \frac{K_{p1}}{K_{p2}} = \frac{4P_1}{2P_1} = 2 \] ### Final Answer Thus, the ratio \( \frac{K_{p1}}{K_{p2}} \) is \( 2 \).

To solve the problem, we need to find the ratio \( \frac{K_{p1}}{K_{p2}} \) given the reactions and conditions provided. Let's break down the solution step by step. ### Step 1: Analyze the first reaction \( A(g) \rightleftharpoons 2B(g) \) 1. **Initial Moles**: Assume at time \( t = 0 \): - Moles of \( A = 1 \) - Moles of \( B = 0 \) ...
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