Home
Class 12
CHEMISTRY
For the reaction A rarr products , the g...

For the reaction `A rarr `products , the graph of the fraction of `A` remaining as a function of time `(x-` axis ) is a straight line with `-ve` slpe . The order of the reaction is therefore

A

1

B

2

C

zero

D

`-1`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the order of the reaction given that the graph of the fraction of A remaining as a function of time is a straight line with a negative slope, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Reaction**: The reaction is given as \( A \rightarrow \text{products} \). We are interested in the concentration of A over time. 2. **Define Initial Conditions**: At time \( t = 0 \), the concentration of A is \( [A]_0 = A \) and the concentration of products is \( [B] = 0 \). 3. **Express Fraction of A Remaining**: At time \( t \), if \( x \) is the amount of A that has reacted, then the concentration of A remaining is: \[ [A] = A - x \] The fraction of A remaining at time \( t \) can be expressed as: \[ \text{Fraction of A remaining} = \frac{[A]}{[A]_0} = \frac{A - x}{A} \] 4. **Graph Interpretation**: The problem states that the graph of the fraction of A remaining as a function of time is a straight line with a negative slope. This indicates a linear relationship between the fraction of A remaining and time. 5. **Linear Equation Form**: A straight line can be expressed in the form: \[ y = mx + c \] where \( y \) is the fraction of A remaining, \( m \) is the slope (negative in this case), \( x \) is time, and \( c \) is the y-intercept. 6. **Identify the Order of Reaction**: For a zero-order reaction, the rate of reaction is constant, and the concentration of A decreases linearly over time. The equation for a zero-order reaction can be written as: \[ [A] = [A]_0 - kt \] which rearranges to show that the fraction of A remaining decreases linearly with time. 7. **Conclusion**: Since the graph is a straight line with a negative slope, this indicates that the reaction is a zero-order reaction. ### Final Answer: The order of the reaction is **zero-order**. ---

To determine the order of the reaction given that the graph of the fraction of A remaining as a function of time is a straight line with a negative slope, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Reaction**: The reaction is given as \( A \rightarrow \text{products} \). We are interested in the concentration of A over time. 2. **Define Initial Conditions**: ...
Promotional Banner

Topper's Solved these Questions

  • CARBONYL COMPOUNDS (ALDEHYDES & KETONES ) & CARBOXYLIC ACID

    RESONANCE ENGLISH|Exercise Part -IV|23 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(Chemistry in every day life)|31 Videos

Similar Questions

Explore conceptually related problems

If t_(1//2) vs (1)/(a^(2)) is a straight line graph then determine the order of reaction.

For a single step reaction X+2Y rarr Products, the molecularity is

A plot of log (a-x) against time 't' is a straight line. This indicates that the reaction is of :

For the reaction A rarr Products, it is found that the rate of reaction increases by a factor of 6.25 when concentration of A increases by a factor of 2.5 . Calculate the order of reaction with respect to A .

For a first order reaction A rarr Products, the half life is 100 seconds. The rate constant of the reaction is

For a hypothetical reaction: A+B rarr Products, the rate law is r = k[A][B]^(0) . The order of reaction is

For a reaction: nA rarr Product, if the rate constant and the rate of reactant are equal what is the order of the reaction?

For a first order reaction, A rarr B , the rate = k xx…………. .

For a chemical reaction A rarr B , the rate of reaction increases by a factor of 1.837 when the concentration of A is increased by 1.5 time. The order of reaction with respect to A is:

For a first order reaction the plot of ‘t’ against log c gives a straight line with a slope equal to :

RESONANCE ENGLISH-CHEMICAL KINETICS-PHYSICAL CHEMITRY (CHEMICAL KNIETICS & RADIOACTIVITY)
  1. A reaction, which is second order,has a rate constant of 0.002 L mol^(...

    Text Solution

    |

  2. In the following reaction A rarr B+C, rate constant is 0.001Ms^(-1). I...

    Text Solution

    |

  3. For the reaction A rarr products , the graph of the fraction of A rema...

    Text Solution

    |

  4. For the zero order reaction A rarr B+C, initial concentration of A is ...

    Text Solution

    |

  5. Decomposition of Hl (g) on Gold surface is zero order reaction. Initia...

    Text Solution

    |

  6. Which of the following statement is incorrect ?

    Text Solution

    |

  7. The rate expression for reaction A(g) +B(g) rarr C(g) is rate =k[A]^(1...

    Text Solution

    |

  8. If rate of diffusion of A is 2 times that of B, what will be the densi...

    Text Solution

    |

  9. If rate of diffusion of A is 10 times that of B, what will be the dens...

    Text Solution

    |

  10. The reaction A(g) + 2B(g) rarr C(g) + D(g) is an elementary process. I...

    Text Solution

    |

  11. If rate of diffusion of A is 11 times that of B, what will be the dens...

    Text Solution

    |

  12. If rate of diffusion of A is 12 times that of B, what will be the dens...

    Text Solution

    |

  13. If rate of diffusion of A is 13 times that of B, what will be the dens...

    Text Solution

    |

  14. The graph between concentration (X) of the Product and time of the rea...

    Text Solution

    |

  15. The rate constant of the reaction A rarr 2B is 1.0 xx 10^(-3) mol "lit...

    Text Solution

    |

  16. At 227^(@)C , the presence of catalyst causes the activation energy of...

    Text Solution

    |

  17. Half life of reaction : H(2)O(2)(aq) rarr H(2)O(l)+(1)/(2)O(2)(g)is in...

    Text Solution

    |

  18. A first order reaction is 20% complete in 10 min. Calculate (a) the sp...

    Text Solution

    |

  19. If rate of diffusion of A is 15 times that of B, what will be the dens...

    Text Solution

    |

  20. Conisder the reaction mechanism: A(2) overset(k(eq))hArr 2A ("fast")...

    Text Solution

    |