Home
Class 12
CHEMISTRY
For the zero order reaction A rarr B+C, ...

For the zero order reaction `A rarr B+C,` initial concentration of A is `0.1A`. If `A=0.08M` after 10 minutes, then it's half`-` life and completion time are respectively `:`

A

10 min, 20 min

B

`2xx10^(-3)` min, `10^(-3)` min

C

25 min, 50 min

D

250 min, 500 min

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to find the half-life and completion time for the zero-order reaction \( A \rightarrow B + C \) given the initial concentration of \( A \) and its concentration after a certain time. ### Step-by-Step Solution: 1. **Identify the given data:** - Initial concentration of \( A \) (\( [A]_0 \)) = 0.1 M - Concentration of \( A \) after 10 minutes (\( [A]_t \)) = 0.08 M - Time (\( t \)) = 10 minutes 2. **Calculate the change in concentration of \( A \):** \[ \Delta [A] = [A]_0 - [A]_t = 0.1 \, \text{M} - 0.08 \, \text{M} = 0.02 \, \text{M} \] 3. **Use the formula for the rate constant \( k \) for a zero-order reaction:** \[ k = \frac{\Delta [A]}{t} = \frac{0.02 \, \text{M}}{10 \, \text{min}} = 0.002 \, \text{M/min} \] 4. **Calculate the completion time:** - The completion time (\( t_{completion} \)) for a zero-order reaction can be calculated using: \[ t_{completion} = \frac{[A]_0}{k} = \frac{0.1 \, \text{M}}{0.002 \, \text{M/min}} = 50 \, \text{minutes} \] 5. **Calculate the half-life (\( t_{1/2} \)) for a zero-order reaction:** - The half-life for a zero-order reaction is given by: \[ t_{1/2} = \frac{t_{completion}}{2} = \frac{50 \, \text{minutes}}{2} = 25 \, \text{minutes} \] ### Final Results: - Half-life (\( t_{1/2} \)) = 25 minutes - Completion time (\( t_{completion} \)) = 50 minutes

To solve the problem, we need to find the half-life and completion time for the zero-order reaction \( A \rightarrow B + C \) given the initial concentration of \( A \) and its concentration after a certain time. ### Step-by-Step Solution: 1. **Identify the given data:** - Initial concentration of \( A \) (\( [A]_0 \)) = 0.1 M - Concentration of \( A \) after 10 minutes (\( [A]_t \)) = 0.08 M - Time (\( t \)) = 10 minutes ...
Promotional Banner

Topper's Solved these Questions

  • CARBONYL COMPOUNDS (ALDEHYDES & KETONES ) & CARBOXYLIC ACID

    RESONANCE ENGLISH|Exercise Part -IV|23 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(Chemistry in every day life)|31 Videos

Similar Questions

Explore conceptually related problems

For the zero order reaction AtoB+C , initial concentration of A is 0.1 M. If [A]=0.08 M after 10 minutes,then its half-life and completion time are respectively :

For a zero order reaction '[R]_0 is the initial concentration

For the first order reaction half-life time is ………….. on the initial concentration.

In a first-order reaction A rarr B , if K is the rate constant and initial concentration of the reactant is 0.5 M , then half-life is

In a first-order reaction A→B, if k is rate constant and initial concentration of the reactant A is 0.5 M then the half-life is:

For a zero order reaction, the half-life periof is independent of the initial concentration.

In a first order reaction A to B, if k is rate constant and initial concentration of the reactant A is 2 M then the half life of the reaction is:

The rate constant for a first order reaction is 5.0×10^(−4)s^(−1) .If initial concentration of reactant is 0.080 M, what is the half life of reaction?

The half-life periof of a first order reaction is…………..of initial concentration.

The half-life period of a ........... order reaction is ..... initial concentration.

RESONANCE ENGLISH-CHEMICAL KINETICS-PHYSICAL CHEMITRY (CHEMICAL KNIETICS & RADIOACTIVITY)
  1. In the following reaction A rarr B+C, rate constant is 0.001Ms^(-1). I...

    Text Solution

    |

  2. For the reaction A rarr products , the graph of the fraction of A rema...

    Text Solution

    |

  3. For the zero order reaction A rarr B+C, initial concentration of A is ...

    Text Solution

    |

  4. Decomposition of Hl (g) on Gold surface is zero order reaction. Initia...

    Text Solution

    |

  5. Which of the following statement is incorrect ?

    Text Solution

    |

  6. The rate expression for reaction A(g) +B(g) rarr C(g) is rate =k[A]^(1...

    Text Solution

    |

  7. If rate of diffusion of A is 2 times that of B, what will be the densi...

    Text Solution

    |

  8. If rate of diffusion of A is 10 times that of B, what will be the dens...

    Text Solution

    |

  9. The reaction A(g) + 2B(g) rarr C(g) + D(g) is an elementary process. I...

    Text Solution

    |

  10. If rate of diffusion of A is 11 times that of B, what will be the dens...

    Text Solution

    |

  11. If rate of diffusion of A is 12 times that of B, what will be the dens...

    Text Solution

    |

  12. If rate of diffusion of A is 13 times that of B, what will be the dens...

    Text Solution

    |

  13. The graph between concentration (X) of the Product and time of the rea...

    Text Solution

    |

  14. The rate constant of the reaction A rarr 2B is 1.0 xx 10^(-3) mol "lit...

    Text Solution

    |

  15. At 227^(@)C , the presence of catalyst causes the activation energy of...

    Text Solution

    |

  16. Half life of reaction : H(2)O(2)(aq) rarr H(2)O(l)+(1)/(2)O(2)(g)is in...

    Text Solution

    |

  17. A first order reaction is 20% complete in 10 min. Calculate (a) the sp...

    Text Solution

    |

  18. If rate of diffusion of A is 15 times that of B, what will be the dens...

    Text Solution

    |

  19. Conisder the reaction mechanism: A(2) overset(k(eq))hArr 2A ("fast")...

    Text Solution

    |

  20. In a reaction A rarr produce, when from 8.0xx10^(-2) M of A, half life...

    Text Solution

    |