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The rate expression for reaction A(g) +B...

The rate expression for reaction `A(g) +B(g) rarr C(g)` is rate `=k[A]^(1//2)[B]^(2)`. What change in rate if initial concentration of `A` and B increases by factor 4 and 2 respectively ?

A

4

B

6

C

8

D

None of these

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The correct Answer is:
To solve the problem, we need to analyze how the rate of the reaction changes when the concentrations of reactants A and B are altered. The rate expression given is: \[ \text{Rate} = k[A]^{1/2}[B]^{2} \] ### Step 1: Identify the initial rate expression The initial rate of the reaction can be expressed as: \[ \text{Rate}_0 = k[A]^{1/2}[B]^{2} \] ### Step 2: Determine the new concentrations The problem states that the concentration of A increases by a factor of 4, and the concentration of B increases by a factor of 2. Therefore, the new concentrations can be expressed as: - New concentration of A: \( [A]_{new} = 4[A] \) - New concentration of B: \( [B]_{new} = 2[B] \) ### Step 3: Substitute the new concentrations into the rate expression Now, we substitute the new concentrations into the rate expression to find the new rate: \[ \text{Rate}_1 = k[4A]^{1/2}[2B]^{2} \] ### Step 4: Simplify the new rate expression Now, we simplify the expression: 1. Calculate \( [4A]^{1/2} \): \[ [4A]^{1/2} = 4^{1/2}[A]^{1/2} = 2[A]^{1/2} \] 2. Calculate \( [2B]^{2} \): \[ [2B]^{2} = 2^{2}[B]^{2} = 4[B]^{2} \] Now, substituting these back into the rate expression: \[ \text{Rate}_1 = k \cdot (2[A]^{1/2}) \cdot (4[B]^{2}) \] ### Step 5: Combine the factors Now, we can combine the factors: \[ \text{Rate}_1 = k \cdot 2 \cdot 4 \cdot [A]^{1/2} \cdot [B]^{2} = 8k[A]^{1/2}[B]^{2} \] ### Step 6: Relate the new rate to the initial rate We can relate the new rate to the initial rate: \[ \text{Rate}_1 = 8 \cdot \text{Rate}_0 \] ### Conclusion Thus, the rate of the reaction increases by a factor of 8 when the concentration of A is increased by a factor of 4 and the concentration of B is increased by a factor of 2. ### Final Answer The rate after the change is **8 times the initial rate**. ---

To solve the problem, we need to analyze how the rate of the reaction changes when the concentrations of reactants A and B are altered. The rate expression given is: \[ \text{Rate} = k[A]^{1/2}[B]^{2} \] ### Step 1: Identify the initial rate expression The initial rate of the reaction can be expressed as: \[ \text{Rate}_0 = k[A]^{1/2}[B]^{2} \] ...
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