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For a chemical reaction A rarr Products,...

For a chemical reaction `A rarr` Products, the rate of disappearance of `A` is given by:
`-(dC_(A))/(dt)=(K_(1)C_(A))/(1+K_(2)C_(A))` At low `C_(A)`, the reaction is of the …. Order with rate constant …..: `("Assume" K_(1), K_(2) "are lesser than" 1)`

A

`I,(K_(1))/(K_(2))`

B

`I,K_(1)`

C

`II,K_(1)//K_(2)`

D

`II,(K_(1))/(K_(1)+K_(2))`

Text Solution

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The correct Answer is:
To solve the problem, we need to analyze the given rate equation and determine the order of the reaction and the rate constant at low concentrations of A. ### Step-by-Step Solution: 1. **Understanding the Rate Equation**: The rate of disappearance of A is given by: \[ -\frac{dC_A}{dt} = \frac{K_1 C_A}{1 + K_2 C_A} \] Here, \(C_A\) is the concentration of A, and \(K_1\) and \(K_2\) are constants. 2. **Assuming Low Concentration of A**: We are told to assume that \(C_A\) is low. Under this condition, \(K_2 C_A\) will also be very small because \(K_2\) is less than 1. Therefore, we can approximate: \[ 1 + K_2 C_A \approx 1 \] 3. **Simplifying the Rate Equation**: Substituting this approximation into the rate equation gives: \[ -\frac{dC_A}{dt} \approx \frac{K_1 C_A}{1} = K_1 C_A \] 4. **Identifying the Order of Reaction**: The simplified equation can be rewritten as: \[ -\frac{dC_A}{dt} = K_1 C_A \] This is in the form of a first-order reaction, which is generally expressed as: \[ \text{Rate} = k C_A^n \] where \(n\) is the order of the reaction. Here, we can see that \(n = 1\). 5. **Determining the Rate Constant**: From the simplified equation, we can identify that the rate constant \(k\) is equal to \(K_1\): \[ k = K_1 \] ### Final Answer: At low \(C_A\), the reaction is of **first order** with rate constant **\(K_1\)**.

To solve the problem, we need to analyze the given rate equation and determine the order of the reaction and the rate constant at low concentrations of A. ### Step-by-Step Solution: 1. **Understanding the Rate Equation**: The rate of disappearance of A is given by: \[ -\frac{dC_A}{dt} = \frac{K_1 C_A}{1 + K_2 C_A} ...
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