Home
Class 12
CHEMISTRY
Graph between log k and 1//T [k rate con...

Graph between `log k` and `1//T` [`k` rate constant `(s^(-1))` and `T` and the temperature `(K)`] is a straight line with `OX =5, theta = tan^(-1) (1//2.303)`. Hence `-E_(a)` will be

A

`2.303xx2 cal`

B

`(2)/(2.303)cal`

C

`2 cal`

D

None of these

Text Solution

Verified by Experts

The correct Answer is:
3

We know, `logK=logA-(E_(a))/(2.303RT)`
compare this by `y=mx+c`
`m=-(E_(a))/(2.303R)`slpe of this
Given `-(E_(a))/(2.303R)=-(1)/(2.303)`
`E_(a)=R=2cal`
Promotional Banner

Topper's Solved these Questions

  • CARBONYL COMPOUNDS (ALDEHYDES & KETONES ) & CARBOXYLIC ACID

    RESONANCE ENGLISH|Exercise Part -IV|23 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(Chemistry in every day life)|31 Videos

Similar Questions

Explore conceptually related problems

Graph between log k and (1)/(T) (k is rate constant in s^(-1) and T is the temperature in K) is a straight line. As shown in figure if OX = 5 and slope of the line =- (1)/(2.303) then E_(a) is :

The graph between log k versus 1//T is a straight line.

The graph between log t_(1//2) and log a at a given temperature is Rate of this reaction will …….with passage of time

Rate constant k varies with temperature by equation log k (min^(-1)) = log 5 - (2000 kcal)/(RT xx 2.303) . We can conclude that

A plot of ln k against (1)/(T) (abscissa) is expected to be a straight line with intercept on coordinate axis equal to

Two reaction : X rarr Products and Y rarr Products have rate constants k_(1) and k_(2) at temperature T and activation energies E_(1) and E_(2) , respectively. If k_(1) gt k_(2) and E_(1) lt E_(2) (assuming that the Arrhenius factor is same for both the Products), then (I) On increaisng the temperature, increase in k_(2) will be greater than increaisng in k_(1) . (II) On increaisng the temperature, increase in k_(1) will be greater than increase in k_(2) . (III) At higher temperature, k_(1) will be closer to k_(2) . (IV) At lower temperature, k_(1) lt k_(2)

In a plot of log k vs 1/T, the slope is

Activation energy (E_a) and rate constants (k_1 and k_2) of a chemical reaction at two different temperature (T_1 and T_2) are related by

RESONANCE ENGLISH-CHEMICAL KINETICS-PHYSICAL CHEMITRY (CHEMICAL KNIETICS & RADIOACTIVITY)
  1. For a chemical reaction A rarr Products, the rate of disappearance of ...

    Text Solution

    |

  2. At the point of intersection of the two curves shown, the conc. of B i...

    Text Solution

    |

  3. The decomposition of N(2)O(5) occurs as, 2N(2)O(5) rarr4NO(2)+O(2) and...

    Text Solution

    |

  4. The rate constant for an isomerization reaction, A rarr B is 4.5 xx 10...

    Text Solution

    |

  5. A hypothetical reaction A(2) + B(2) rarr 2AB follows the mechanism as ...

    Text Solution

    |

  6. For an exothermic chemical process ocuuring in two process occuring in...

    Text Solution

    |

  7. For the reaction , 2NO2+F5rarr 2NO2F following mechanism has been pro...

    Text Solution

    |

  8. For the reaction, 2NO(g) + 2H(2)(g) rarr N(2)(g) + 2H(2)O(g) The ...

    Text Solution

    |

  9. What will be the order of reaction and rate constant for a chemical ch...

    Text Solution

    |

  10. The unit of rate constant of elementary reaction depends upon the:

    Text Solution

    |

  11. For an elementary reaction 2A+BtoA(2)B if the volume of vessel is quic...

    Text Solution

    |

  12. The decomposition of azo methane, at certain temperature according to ...

    Text Solution

    |

  13. For a complex reaction A overset(k) rarr products E(a1)=180kJ //mol ...

    Text Solution

    |

  14. Atoms .(7)^(A)X, (8)^(B)Y " and " (9)^(17)Z are such that .(8)Y is an ...

    Text Solution

    |

  15. The number of neutrons accompanying the formation of .(54)Xe^(139) and...

    Text Solution

    |

  16. A sample of radiative substance is found 90% of it’s initial amount af...

    Text Solution

    |

  17. For a given reaction A rarr Product, rate is 1xx10^(-4)M s^(-1) when ...

    Text Solution

    |

  18. Milk turns sour at 40^(@)C three times as faster as 0^(@)C. Hence E(a)...

    Text Solution

    |

  19. Graph between log k and 1//T [k rate constant (s^(-1)) and T and the t...

    Text Solution

    |

  20. In a first order reaction, the concentrations of the reactant, 30 minu...

    Text Solution

    |