Home
Class 12
CHEMISTRY
Mixture of volatile components A and B h...

Mixture of volatile components A and B has total pressure ( in Torr ) `p=265-130x_(A),` where `X_(A)` is mole fraction of `A` in mixture . Hence `P_(A)^(@)+P_(B)^(@)=` ( in T o r r).

A

265

B

135

C

400

D

150

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to find the sum of the vapor pressures of components A and B, denoted as \( P_0^A + P_0^B \). ### Step-by-Step Solution: 1. **Understand the Total Pressure Equation**: The total pressure \( P \) of the mixture is given by the equation: \[ P = 265 - 130x_A \] where \( x_A \) is the mole fraction of component A. 2. **Apply Raoult's Law**: According to Raoult's law, the total pressure \( P_T \) can also be expressed as: \[ P_T = P_0^A x_A + P_0^B x_B \] where \( P_0^A \) and \( P_0^B \) are the vapor pressures of pure components A and B, respectively, and \( x_B = 1 - x_A \). 3. **Substitute \( x_B \)**: Substitute \( x_B \) in the equation: \[ P_T = P_0^A x_A + P_0^B (1 - x_A) \] Simplifying this gives: \[ P_T = P_0^A x_A + P_0^B - P_0^B x_A \] Rearranging, we have: \[ P_T = (P_0^B - P_0^A) x_A + P_0^B \] 4. **Set the Two Expressions for Total Pressure Equal**: We have two expressions for \( P_T \): \[ 265 - 130x_A = (P_0^B - P_0^A) x_A + P_0^B \] 5. **Compare Coefficients**: From the equation above, we can compare coefficients of \( x_A \) and the constant terms: - Coefficient of \( x_A \): \[ -130 = P_0^B - P_0^A \quad \text{(1)} \] - Constant term: \[ P_0^B = 265 \quad \text{(2)} \] 6. **Substitute \( P_0^B \) into Equation (1)**: Substitute \( P_0^B = 265 \) into equation (1): \[ -130 = 265 - P_0^A \] Rearranging gives: \[ P_0^A = 265 + 130 = 395 \] 7. **Calculate \( P_0^A + P_0^B \)**: Now, we can find the sum of the vapor pressures: \[ P_0^A + P_0^B = 395 + 265 = 660 \] ### Final Answer: Thus, the sum of the vapor pressures \( P_0^A + P_0^B \) is: \[ \boxed{660 \text{ Torr}} \]

To solve the problem, we need to find the sum of the vapor pressures of components A and B, denoted as \( P_0^A + P_0^B \). ### Step-by-Step Solution: 1. **Understand the Total Pressure Equation**: The total pressure \( P \) of the mixture is given by the equation: \[ P = 265 - 130x_A ...
Promotional Banner

Topper's Solved these Questions

  • SOLID STATE

    RESONANCE ENGLISH|Exercise PHYSICAL CHEMITRY (SOLID STATE)|45 Videos
  • SOLUTIONS

    RESONANCE ENGLISH|Exercise Advabced Level Problems (PART-2)|35 Videos

Similar Questions

Explore conceptually related problems

Mixture of volatile components A and B has a total vapour pressure (in torr)p= 254-119 x_(A) is where x_(A) mole fraction of A in mixture .Hence P_(A)^@ and P_(B)^@ are(in torr)

Mixture of volatile components A and B has a total vapour pressure (in torr)p= 254-119 x_(A) is where x_(A) mole fraction of A in mixture .Hence P_(A)^@ and P_(B)^@ are(in torr)

Vapour pressure of mixture of liquid A and liquid B at 70^(@)C is given by P_(T)=180X_(B)+90 (in mm) . Where X_(B) is the mole fraction of B, in the liquid mixture. Calculate (a) Vapour pressure of pure A and pure B (b) Vapour pressure of mixture of A and B by mixing 4 g and 12 g B. (If molar mass of A and B are 2 g and 3 g respectively) (c ) From (b) ratio of moles of A and B in vapour at 70^(@)C

For an ideal solution, if a graph is plotted between (1)/(P_(T)) and y_(A) (mole fraction of A in vapour phase) where p_(A)^(0)gtp_(B)^(0) then

At 40^(@)C , vapour pressure in Torr of methanol and ethanol solution is P=119x+135 where x is the mole fraction of methanol. Hence

P_(A)=(235y -125xy)mm of HgP_(A) is partial pressure of A,x is mole fraction of B in liquid phase in the mixture of two liquids A and B and y is the mole fraction of A in vapour phase, then P_(B)^(@) in mm of Hg is:

For a gaseous reaction aA(g)+bB(g)hArrcC(g)+dD(g) equilibrium constants K_(c),K_(p) and K_(x) are represented by the following reation K_(c)=([C]^(c)[D]^(d))/([A]^(a)[B]^(b)),K_(p)=(Pc^(c).P_(D)^(d))/P_(A)^(a) and Kx=(x_(C)^(c).x_(D)^(d))/(x_(A)^(a).x_(B)^(b) where [A] represents molar concentrationof A,p_(A) represents partial pressure of A and P represents total pressure, x_(A) represents mole fraction of A For the reaction SO_(2)Cl_(2)(g)hArrSO_(2)(g)+Cl_(2)(g),K_(p)gtK_(x) is obtained at :

The rates of diffusion of two gases A and B are in the the ratio 1:4 A mixture contains these gases A and B in the ratio 2:3 The ratio of mole fraction of the gases A and B in the mixture is (assume that P_(A) =P_(B)) .

At 40^(@)C , the vapour pressures in torr, of methyl alcohol and ethyl alcohol solutions is represented by the equation. P = 119X_(A) + 135 where X_(A) is mole fraction of methyl alcohol, then the value of underset(x_(A)rarr1)(lim)(P_(A))/(X_(A)) is

Liquids A and B form ideal solution over the entire range of composition. At temperature T, equimolar binary solution of liquids A and B has vapour pressure 45 torr. At the same temperature, a new solution of A and B having mole fractions x_(A) and x_(B) , respectively, has vapours pressure of 22.5 torr. The value of x_(A)//x_(B) in the new solution is ______. (Given that the vapour pressure of pure liquid A is 20 torr at temperature T).

RESONANCE ENGLISH-SOLUTION AND COLLIGATIVE PROPERTIES-PHYSICAL CHEMITRY (SOLUTION & COLLIGATIVE PROPERTIES)
  1. What weight of glucose dissolved in 100 grams of water will produce th...

    Text Solution

    |

  2. The plots of (1)/(X(A))vs.(1)/(Y(A)) (where X(A) and Y(A) are the mole...

    Text Solution

    |

  3. Mixture of volatile components A and B has total pressure ( in Torr ) ...

    Text Solution

    |

  4. What is the mole ratio of benzene (P(B)^(@)=150 t o r r) and toluence...

    Text Solution

    |

  5. In which case, van't Hoff factor I remains unchanged ? ( Assume common...

    Text Solution

    |

  6. The vapor pressures of benzenen, toluene and ortho xylene are 75 Torr,...

    Text Solution

    |

  7. The freezing point depression constant for water is -1.86^(@)C m^(-1)....

    Text Solution

    |

  8. Depression of freezing point of which of the following solutions doe...

    Text Solution

    |

  9. An aqueous solution containing liquid A(M.Wt.=128)64% by weight has a ...

    Text Solution

    |

  10. We have a 0.1M solution of NH(2)CONH(2),H(3)PO(3) and H(3)PO(4) then w...

    Text Solution

    |

  11. Which solution will show the maximum vapour pressure at 300K

    Text Solution

    |

  12. An aqueous solution containing 21.6 mg at a solute in 100 ml of soluti...

    Text Solution

    |

  13. At 300K ,36g of glucose present in a litre of its solution has an osmo...

    Text Solution

    |

  14. The Vapour pressure of solution containing 2g of NaCl in 100g of water...

    Text Solution

    |

  15. 5g each of two solutes X and Y ( mol. wt of X gt Y) are dissolved in ...

    Text Solution

    |

  16. A complex containing K,Pt(IV) and Cl^(-) is 100% ionized giving i=3 th...

    Text Solution

    |

  17. The azeotropic mixture of water (b.pt 100^(@)C) and HCl (b.pt 85^(@)C)...

    Text Solution

    |

  18. If the freezing point of 0.1 M HA(aq) solution is -0.2046^(@)C then pH...

    Text Solution

    |

  19. The lowest concentration of oxygen that can support aquatic life is ab...

    Text Solution

    |

  20. The ratio aof Delta T(f) [ Fe(CN)(6)] solution ( assuming complete ion...

    Text Solution

    |