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The freezing point of 0.08 molal aq NaHS...

The freezing point of 0.08 molal aq `NaHSO_(4)` solution is `-0.372`. Calculate `alpha` (degree of dessociation) of `HSO_(4)^(-)` given `alpha` (degree of dissociation) of `NaHSO_(4)` is `100%` & `K_(f)` for `H_(2)O=1.86` `(K)/(m)`. Give answer after multiplying by 10.

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To solve the problem, we need to calculate the degree of dissociation (α) of the bisulfate ion (HSO₄⁻) in a 0.08 molal aqueous solution of sodium bisulfate (NaHSO₄). We are given that the freezing point depression is -0.372°C and the cryoscopic constant (K_f) of water is 1.86 K·kg/mol. ### Step-by-Step Solution: 1. **Identify the Dissociation of NaHSO₄:** Sodium bisulfate (NaHSO₄) dissociates in water as follows: \[ \text{NaHSO}_4 \rightarrow \text{Na}^+ + \text{HSO}_4^- \] The bisulfate ion (HSO₄⁻) can further dissociate: \[ \text{HSO}_4^- \rightleftharpoons \text{H}^+ + \text{SO}_4^{2-} \] 2. **Define the Degree of Dissociation (α):** Let α be the degree of dissociation of HSO₄⁻. After dissociation: - The concentration of Na⁺ ions = 1 (from NaHSO₄) - The concentration of HSO₄⁻ ions = 1 - α - The concentration of H⁺ ions = α - The concentration of SO₄²⁻ ions = α 3. **Calculate the Total Number of Ions (i):** The total number of ions after dissociation is: \[ i = 1 + (1 - α) + α + α = 2 + α \] 4. **Use the Freezing Point Depression Formula:** The formula for freezing point depression is given by: \[ \Delta T_f = i \cdot K_f \cdot m \] Where: - \(\Delta T_f = 0 - (-0.372) = 0.372\) - \(K_f = 1.86 \, \text{K·kg/mol}\) - \(m = 0.08 \, \text{mol/kg}\) 5. **Plug in the Values:** Substitute the known values into the freezing point depression equation: \[ 0.372 = (2 + α) \cdot 1.86 \cdot 0.08 \] 6. **Solve for α:** Rearranging the equation: \[ 0.372 = (2 + α) \cdot 0.1488 \] \[ 2 + α = \frac{0.372}{0.1488} \approx 2.5 \] \[ α = 2.5 - 2 = 0.5 \] 7. **Multiply α by 10:** The final step is to multiply α by 10: \[ 10α = 10 \times 0.5 = 5 \] ### Final Answer: The answer after multiplying by 10 is **5**.
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