Home
Class 12
CHEMISTRY
An ideal monoatomic gas initially in sta...

An ideal monoatomic gas initially in state 1 with pressure `P_(1)=20` atm and volume `V_(1)1500cm^(3)` it is then taken to state 2 with pressure `P_(2)=1.5P_(1)` and volume `V_(2)=2V_(1)` find the change in internal energy in this process in KJ. (take `1atm` lit `=100J`)

Text Solution

AI Generated Solution

The correct Answer is:
To find the change in internal energy of the ideal monoatomic gas during the process from state 1 to state 2, we will follow these steps: ### Step 1: Identify the initial and final states - Initial state (State 1): - Pressure, \( P_1 = 20 \) atm - Volume, \( V_1 = 1500 \) cm³ - Final state (State 2): - Pressure, \( P_2 = 1.5 P_1 = 1.5 \times 20 = 30 \) atm - Volume, \( V_2 = 2 V_1 = 2 \times 1500 = 3000 \) cm³ ### Step 2: Use the formula for change in internal energy The change in internal energy (\( \Delta E \)) for an ideal monoatomic gas is given by: \[ \Delta E = N C_v \Delta T \] Where: - \( C_v \) for a monoatomic gas = \( \frac{3}{2} R \) - \( \Delta T = T_2 - T_1 \) ### Step 3: Calculate temperatures \( T_1 \) and \( T_2 \) Using the ideal gas law \( PV = nRT \), we can express temperatures as: \[ T_1 = \frac{P_1 V_1}{nR} \] \[ T_2 = \frac{P_2 V_2}{nR} \] ### Step 4: Substitute \( T_1 \) and \( T_2 \) into the equation for \( \Delta E \) Substituting the expressions for \( T_1 \) and \( T_2 \) into the equation for \( \Delta E \): \[ \Delta E = N C_v \left( \frac{P_2 V_2}{nR} - \frac{P_1 V_1}{nR} \right) \] This simplifies to: \[ \Delta E = N \frac{3}{2} R \left( \frac{P_2 V_2 - P_1 V_1}{nR} \right) \] \[ \Delta E = N \frac{3}{2} \left( P_2 V_2 - P_1 V_1 \right) \] ### Step 5: Calculate \( P_2 V_2 \) and \( P_1 V_1 \) Now, we calculate: \[ P_1 V_1 = 20 \, \text{atm} \times 1500 \, \text{cm}^3 = 30000 \, \text{atm cm}^3 \] \[ P_2 V_2 = 30 \, \text{atm} \times 3000 \, \text{cm}^3 = 90000 \, \text{atm cm}^3 \] ### Step 6: Find \( \Delta E \) Now substituting these values: \[ \Delta E = N \frac{3}{2} (90000 - 30000) = N \frac{3}{2} \times 60000 = N \times 90000 \] ### Step 7: Convert units Since \( 1 \, \text{atm} \, \text{cm}^3 = 100 \, \text{J} \): \[ \Delta E = 90000 \, \text{atm cm}^3 \times 100 \, \text{J/atm cm}^3 = 9000000 \, \text{J} \] Convert to kilojoules: \[ \Delta E = \frac{9000000 \, \text{J}}{1000} = 9000 \, \text{kJ} \] ### Final Answer The change in internal energy in this process is \( 9 \, \text{kJ} \). ---

To find the change in internal energy of the ideal monoatomic gas during the process from state 1 to state 2, we will follow these steps: ### Step 1: Identify the initial and final states - Initial state (State 1): - Pressure, \( P_1 = 20 \) atm - Volume, \( V_1 = 1500 \) cm³ - Final state (State 2): ...
Promotional Banner

Topper's Solved these Questions

  • TEST PAPERS

    RESONANCE ENGLISH|Exercise PT-01|30 Videos
  • TEST PAPERS

    RESONANCE ENGLISH|Exercise Pt-02|30 Videos
  • TEST PAPERS

    RESONANCE ENGLISH|Exercise PART - III CHEMISTRY|20 Videos
  • SURFACE CHEMISTRY

    RESONANCE ENGLISH|Exercise Section - 5|1 Videos
  • TEST SERIES

    RESONANCE ENGLISH|Exercise CHEMISTRY|50 Videos

Similar Questions

Explore conceptually related problems

An ideal monoatomic gas is initially in state 1 with pressure p_(1) = 20 atm and volume v_(1) = 1500 cm^(3) . If is then taken to state 2 with pressure p_(2) = 1.5 p_(1) and volume v_(2) = 2v_(1) . The change in internal energy from state 1 to state 2 is equal to

A monoatomic gas at pressure P_(1) and volume V_(1) is compressed adiabatically to 1/8th of its original volume. What is the final pressure of gas.

The pressure P and volume V of an ideal gas both decreases in a process.

An ideal monoatomic gas follows a thermodynamic process as shown in pressure-volume (P-V) plot. The work done in process AB is

A gas is at 1 atm pressure with a volume 800 cm^(3) . When 100 J of heat is supplied to the gas, it expands to 1L at constant pressure. The change in its internal energy is

A gas is at 1 atm pressure with a volume 800 cm^(3) . When 100 J of heat is supplied to the gas, it expands to 1L at constant pressure. The change in its internal energy is

The pressure p and volume V of an ideal gas both increase in a process.

Two moles of an ideal monoatomic gas, initially at pressure p_1 and volume V_1 , undergo an adiabatic compression until its volume is V_2 . Then the gas is given heat Q at constant volume V_2 . (i) Sketch the complete process on a p-V diagram. (b) Find the total work done by the gas, the total change in its internal energy and the final temperature of the gas. [Give your answer in terms of p_1,V_1,V_2, Q and R ]

One mole of hydrogen, assumed to be ideal, is adiabatically expanded from its initial state (P_(1), V_(1), T_(1)) to the final state (P_(2), V_(2), T_(2)) . The decrease in the internal energy of the gas during this process will be given by

An ideal gas ((C_(p))/(C_(v))=gamma) has initial volume V_(0) is kept in a vessel. It undergoes a change and follows the following relation P = kV^(2) (where P is pressure, and V is volume) find the change in internal energy of the gas if its final pressure is P_(0) :

RESONANCE ENGLISH-TEST PAPERS-Chemistry
  1. Conductivity of a saturated solution of a sparingly soluble salt AB at...

    Text Solution

    |

  2. In the arrangement given below 20 mole of N(2) and 5 mole of He are pr...

    Text Solution

    |

  3. An ideal monoatomic gas initially in state 1 with pressure P(1)=20 atm...

    Text Solution

    |

  4. How many of the following are bidentate ligan? Oxalate, Glycinate, H...

    Text Solution

    |

  5. Which of the following can act as ambidentate ligand? I^(-),NO(2)^(-...

    Text Solution

    |

  6. Total number of stereoisomers of given compound are:

    Text Solution

    |

  7. Define structure and hybridization of PCl(5)

    Text Solution

    |

  8. In following how many structures are chiral?

    Text Solution

    |

  9. Calculate the hydrolysis constant of NH4Cl. Determine the degree of hy...

    Text Solution

    |

  10. How many total possible products are formed in following reaction: C...

    Text Solution

    |

  11. State True or false a chiral carbon consists of 4 different groups A...

    Text Solution

    |

  12. A group two element M forms a carbide which is actually a methanide (i...

    Text Solution

    |

  13. Which of the following represent(s) bidentate ligand(s)?

    Text Solution

    |

  14. Mark the correct statements(s) regarding Azeotropes

    Text Solution

    |

  15. A hexa-coordinated complex of formula CoCl(3).6H(2)O undergoes 100% io...

    Text Solution

    |

  16. the red coloured Wilkinson's catalyst, [RhCl(PPh(3))(3)] is a homogeno...

    Text Solution

    |

  17. Which of the following IUPAC names(s) is/are not correctly matched wit...

    Text Solution

    |

  18. Energy profile diagram for an exothermic reaction. Aoverset(1)toBovers...

    Text Solution

    |

  19. Consider the following compound: The set of compound/s which give at...

    Text Solution

    |

  20. overset19 8X atom is isotonic to oversety 7Y atom. The value of y is...

    Text Solution

    |