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Which of the following is/are correct fo...

Which of the following is/are correct for the water insoluble yellow coloured complex `K_(2)[PtCl_(6)]`?

A

It is an innter orbital complex.

B

it is high spin complex.

C

its IUPAC name is potassium hexachloridoplatinum (IV).

D

it is homoleptic complex.

Text Solution

Verified by Experts

The correct Answer is:
A, D
For `4d//5d` metals all ligands act as strong field ligand (sfi) `Pt^(4+):5d^(6)`: pairing occurs `d^(2)sp^(3)` inner orbital los spin homoleptic (because only one type of ligand is present)
IUPAC name: potassium hexachloridoplatinate (IV) because coordination sphere is anionic.
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