In which of the following cordination en...

In which of the following cordination entities, the magnitude of `Delta_(0)[CFSE` in octahedral field] will be maximum ?

`14mL`

`12.72mL`

`11.31mL`

`15mL`

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The correct Answer is:

The volume of the gas in the bubble remains constant, so that `n_(1)=n_(2)`. To calculate the final volume , `V_(2)`,
`V_(2)=V_(1)xx(P_(1))/(P_(2))xx(T_(2))/(T_(1))`
`=2.0mL xx(6.0atm)/(1.0atm)xx(280K)/(281K)=12.72mL`

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In which of the following cordination entities, the magnitude of `Delta_(0)[CFSE` in octahedral field] will be maximum ?

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