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Match the List -I (containing anions ) w...

Match the List -I (containing anions ) with List -II (containing reagent used in testing ) using the codes as given below in the column.
`{:("List"-I,,"List"-II),(("anions"),,("reagents")),((a)S^(2-),,(p)"Barium chloride solution in presence of HCl"),((b)NO_(3)^(-),,(q)"Sodium nitroprusside"),((c)I^(-),,(r)"chlorine water and chloroform"),((d)SO_(4)^(2-),,(s)"iron"(II)"sulphate solution and conc."H_(2)SOS_(4)):}`
Code `:`

A

`{:(,"(a)","(b)","(c)","(d)"),(,"(q)","(s)","(r)","(p)"):}`

B

`{:(,"(a)","(b)","(c)","(d)"),(,"(p)","(s)","(r)","(q)"):}`

C

`{:(,"(a)","(b)","(c)","(d)"),(,"(q)","(p)","(r)","(s)"):}`

D

`{:(,"(a)","(b)","(c)","(d)"),(,"(p)","(q)","(r)","(s)"):}`

Text Solution

AI Generated Solution

The correct Answer is:
To match the anions from List-I with the appropriate reagents from List-II, we will analyze each anion and determine the correct testing reagent based on the information provided. ### Step-by-Step Solution: 1. **Identify the Anion: Sulfide Ion (S²⁻)** - **Reagent:** Sodium nitroprusside - **Explanation:** The presence of sulfide ions can be detected by treating the sample with sodium nitroprusside, which forms a violet-colored complex. - **Match:** (a) S²⁻ → (q) Sodium nitroprusside 2. **Identify the Anion: Nitrate Ion (NO₃⁻)** - **Reagent:** Iron(II) sulfate solution and concentrated sulfuric acid - **Explanation:** For nitrate ions, when treated with freshly prepared iron(II) sulfate and concentrated sulfuric acid, a brown ring complex is formed at the junction of the two liquids, indicating the presence of nitrate ions. - **Match:** (b) NO₃⁻ → (s) Iron(II) sulfate solution and concentrated H₂SO₄ 3. **Identify the Anion: Iodide Ion (I⁻)** - **Reagent:** Chlorine water and chloroform - **Explanation:** The presence of iodide ions can be detected using chlorine water, which oxidizes iodide ions to iodine (I₂). The iodine dissolves in chloroform, forming a violet layer. - **Match:** (c) I⁻ → (r) Chlorine water and chloroform 4. **Identify the Anion: Sulfate Ion (SO₄²⁻)** - **Reagent:** Barium chloride solution in presence of HCl - **Explanation:** When sulfate ions are treated with barium chloride, a white precipitate of barium sulfate (BaSO₄) is formed, indicating the presence of sulfate ions. - **Match:** (d) SO₄²⁻ → (p) Barium chloride solution in presence of HCl ### Final Matches: - (a) S²⁻ → (q) Sodium nitroprusside - (b) NO₃⁻ → (s) Iron(II) sulfate solution and concentrated H₂SO₄ - (c) I⁻ → (r) Chlorine water and chloroform - (d) SO₄²⁻ → (p) Barium chloride solution in presence of HCl ### Codes: - A: q - B: s - C: r - D: p

To match the anions from List-I with the appropriate reagents from List-II, we will analyze each anion and determine the correct testing reagent based on the information provided. ### Step-by-Step Solution: 1. **Identify the Anion: Sulfide Ion (S²⁻)** - **Reagent:** Sodium nitroprusside - **Explanation:** The presence of sulfide ions can be detected by treating the sample with sodium nitroprusside, which forms a violet-colored complex. - **Match:** (a) S²⁻ → (q) Sodium nitroprusside ...
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