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pH of a saturated solution fo magnesium ...

pH of a saturated solution fo magnesium hydroxide in water at
`298K` is 10. The solubility of the hydroxide in water at 298 K is

A

`5xx10^(-5)molL^(-1)`

B

`5xx10^(-12)molL^(-1)`

C

`1xx10^(-4)molL^(-1)`

D

`1xx10^(-10)molL^(-1)`

Text Solution

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The correct Answer is:
To find the solubility of magnesium hydroxide (Mg(OH)₂) in water at 298 K given that the pH of a saturated solution is 10, we can follow these steps: ### Step-by-Step Solution: 1. **Determine the pOH from the given pH:** \[ \text{pOH} = 14 - \text{pH} = 14 - 10 = 4 \] **Hint:** Remember that pH + pOH = 14 at 25°C (298 K). 2. **Calculate the concentration of hydroxide ions (OH⁻):** \[ \text{pOH} = -\log[\text{OH}^-] \] Rearranging gives: \[ [\text{OH}^-] = 10^{-\text{pOH}} = 10^{-4} \, \text{mol/L} \] **Hint:** Use the definition of pOH to find the concentration of hydroxide ions. 3. **Set up the dissociation equation for magnesium hydroxide:** \[ \text{Mg(OH)}_2 \rightleftharpoons \text{Mg}^{2+} + 2\text{OH}^- \] If the solubility of Mg(OH)₂ is \( S \), then: - The concentration of Mg²⁺ ions will be \( S \). - The concentration of OH⁻ ions will be \( 2S \). **Hint:** Remember that for every mole of Mg(OH)₂ that dissolves, it produces one mole of Mg²⁺ and two moles of OH⁻. 4. **Relate the concentration of OH⁻ to solubility:** Since we found that the concentration of OH⁻ is \( 10^{-4} \, \text{mol/L} \), we can set up the equation: \[ 2S = 10^{-4} \] **Hint:** Use the stoichiometry from the dissociation equation to relate the solubility to the concentration of hydroxide ions. 5. **Solve for the solubility \( S \):** \[ S = \frac{10^{-4}}{2} = 5 \times 10^{-5} \, \text{mol/L} \] **Hint:** Divide the concentration of hydroxide ions by 2 to find the solubility of magnesium hydroxide. ### Final Answer: The solubility of magnesium hydroxide in water at 298 K is \( 5 \times 10^{-5} \, \text{mol/L} \).

To find the solubility of magnesium hydroxide (Mg(OH)₂) in water at 298 K given that the pH of a saturated solution is 10, we can follow these steps: ### Step-by-Step Solution: 1. **Determine the pOH from the given pH:** \[ \text{pOH} = 14 - \text{pH} = 14 - 10 = 4 \] ...
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