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An inorganic iodide (A) on heating with ...

An inorganic iodide (A) on heating with a solution of KOH gives a gas (B) and a solution of a compound. The gas (B) on ignition in air gives a compound (C ) and water. Copper sulphate is finally reduced to the metal on passing (B) through its solution.
The compound (C ) :

A

has `sp^(3)` hydbridisation of central atom(s)

B

has sixteen sigma bonds.

C

is used as a dehydrating agent.

D

all of these.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will identify the compounds A, B, and C based on the information provided in the question. ### Step 1: Identify Compound A The question states that an inorganic iodide (A) reacts with KOH to produce a gas (B) and a solution of a compound. A common inorganic iodide that fits this description is phosphonium iodide (PH₄I). **Reaction:** \[ \text{PH}_4\text{I} + \text{KOH} \rightarrow \text{PH}_3 + \text{H}_2\text{O} + \text{KI} \] ### Step 2: Identify Compound B From the reaction above, we see that the gas (B) produced is phosphine (PH₃). ### Step 3: Identify Compound C The gas (B), which is phosphine (PH₃), is ignited in air. When phosphine burns in the presence of oxygen, it forms phosphorus pentoxide (P₂O₅) and water. **Reaction:** \[ 4 \text{PH}_3 + 6 \text{O}_2 \rightarrow 2 \text{P}_2\text{O}_5 + 6 \text{H}_2\text{O} \] Thus, the compound (C) formed is phosphorus pentoxide (P₂O₅). ### Step 4: Reduction of Copper Sulfate The question also states that copper sulfate (CuSO₄) is reduced to copper metal when phosphine (B) is passed through its solution. This is consistent with the reducing properties of phosphine. **Reaction:** \[ 3 \text{CuSO}_4 + 2 \text{PH}_3 \rightarrow \text{Cu}_3\text{P}_2 + 3 \text{H}_2\text{SO}_4 \] ### Conclusion Based on the above steps, we conclude that: - Compound A is phosphonium iodide (PH₄I). - Compound B is phosphine (PH₃). - Compound C is phosphorus pentoxide (P₂O₅). ### Final Answer The compound (C) is **P₂O₅** (phosphorus pentoxide).
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