Home
Class 12
CHEMISTRY
{:("Column I","Column II"),((A)PbO(2)+HN...

`{:("Column I","Column II"),((A)PbO_(2)+HNO_(3)to,(p)"One of the products has bond order of two." ),((B)Cr_(2)O_(7)^(2-)+H^(+)+H_(2)O_(2)to,(q)"One of the products has peroxide linkages(s)."),((C)H_(2)O_(2)+CIO_(2)+OH^(-)to,(r)"One of the products is a hydride and is liquid at room temperature."),((D)XeF_(2)+NaOH to,(s)"One of the products has bent shape with two lone pairs of electrons on central atom".):}`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given question, we will analyze each reaction in Column I and determine which statements from Column II correspond to the products formed in each reaction. ### Step 1: Analyze the first reaction (A) **Reaction:** PbO₂ + HNO₃ → Products **Products formed:** When lead dioxide (PbO₂) reacts with nitric acid (HNO₃), the products are lead nitrate (Pb(NO₃)₂), water (H₂O), and oxygen (O₂). **Analysis of products:** - **O₂** has a bond order of 2 (double bond). - **H₂O** is a hydride and is liquid at room temperature. - **H₂O** has a bent shape with two lone pairs on the oxygen atom. **Conclusion for A:** - P: True (O₂ has bond order of 2) - R: True (H₂O is a hydride and liquid at room temperature) - S: True (H₂O has bent shape with two lone pairs) - Q: False (No peroxide linkages) **Answer for A:** P, R, S ### Step 2: Analyze the second reaction (B) **Reaction:** Cr₂O₇²⁻ + H⁺ + H₂O₂ → Products **Products formed:** The reaction produces chromium pentoxide (CrO₅) and water (H₂O). **Analysis of products:** - **CrO₅** contains peroxide linkages (O-O bonds). - **H₂O** is a hydride and is liquid at room temperature. - **H₂O** has a bent shape with two lone pairs on the oxygen atom. **Conclusion for B:** - P: False (No product has bond order of 2) - Q: True (CrO₅ has peroxide linkages) - R: True (H₂O is a hydride and liquid at room temperature) - S: True (H₂O has bent shape with two lone pairs) **Answer for B:** Q, R, S ### Step 3: Analyze the third reaction (C) **Reaction:** H₂O₂ + ClO₂ + OH⁻ → Products **Products formed:** The reaction produces ClO₂⁻, water (H₂O), and oxygen (O₂). **Analysis of products:** - **O₂** has a bond order of 2. - **H₂O** is a hydride and is liquid at room temperature. - **H₂O** has a bent shape with two lone pairs on the oxygen atom. **Conclusion for C:** - P: True (O₂ has bond order of 2) - Q: False (No peroxide linkages) - R: True (H₂O is a hydride and liquid at room temperature) - S: True (H₂O has bent shape with two lone pairs) **Answer for C:** P, R, S ### Step 4: Analyze the fourth reaction (D) **Reaction:** XeF₂ + NaOH → Products **Products formed:** The reaction produces xenon (Xe), water (H₂O), and sodium fluoride (NaF). **Analysis of products:** - **O₂** is not produced, but water is produced. - **H₂O** is a hydride and is liquid at room temperature. - **H₂O** has a bent shape with two lone pairs on the oxygen atom. **Conclusion for D:** - P: True (O₂ is released) - Q: False (No peroxide linkages) - R: True (H₂O is a hydride and liquid at room temperature) - S: True (H₂O has bent shape with two lone pairs) **Answer for D:** P, R, S ### Final Summary of Answers: - A: P, R, S - B: Q, R, S - C: P, R, S - D: P, R, S

To solve the given question, we will analyze each reaction in Column I and determine which statements from Column II correspond to the products formed in each reaction. ### Step 1: Analyze the first reaction (A) **Reaction:** PbO₂ + HNO₃ → Products **Products formed:** When lead dioxide (PbO₂) reacts with nitric acid (HNO₃), the products are lead nitrate (Pb(NO₃)₂), water (H₂O), and oxygen (O₂). ...
Promotional Banner

Topper's Solved these Questions

  • P BLOCK ELEMENTS

    RESONANCE ENGLISH|Exercise ALP PART OBJECTIVE|12 Videos
  • P BLOCK ELEMENTS

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(Nitrogen containing Compounds)|5 Videos
  • P BLOCK ELEMENTS

    RESONANCE ENGLISH|Exercise ALP PART II SUBJECTIVE|1 Videos
  • NUCLEAR CHEMISTRY

    RESONANCE ENGLISH|Exercise STAGE-II|1 Videos
  • P-BLOCK ELEMENT (BORON AND CARBON FAMILY)

    RESONANCE ENGLISH|Exercise PART - III : OLYMPIAD PROBLEMS (PREVIOUS YEARS) STAGE - V (INTERNATIONAL CHEMISTRY OLYMPIAD (IChO)) Problem 3|8 Videos

Similar Questions

Explore conceptually related problems

K_(2)Cr_(2)O_(7), + l^(-) + H^(+ )to Oxidized product. The product is

{:("Column I","Column II"),((A)2NO_(2)overset("Cool")to,(p)"One of the products is a mixed anhydride ." ),((B)CIO_(2)+O_(3)overset(H^(+))to,(q)"One of the products is an acidic oxide."),((C)K_(4)[Fe(CN)_(6)]+H_(2)SO_(4)("conc".)+H_(2)Ooverset(Delta)to,(r)"The oxidation state of the central atom of one of the products is +6."),((D)KOH+O_(3)to,(s)"One of the products is a colourless paramagnetic gas".):}

When H_(2)O_(2) is oxidesed, the product is

Identify the product in the reaction HC-=CH overset(K_(2)Cr_(2)O_(7)+H_(2)SO_(4))underset([O])to "Product"

Number of peroxide linkage in CrO_(5), H_(2)SO_(5), H_(2)S_(2)O_(8) are respectively :-

CH_(2) = CH_(2) + B_(2) H_(6) underset(H_(2)O_(2))overset(NaOH) to Product is :

The products of the chemical reaction between Na_(2)S_(2)O_(3) , Cl_(2) and H_(2)O are

Give the products formed on reduction with LAH and oxidation with H_(2)O_(2) , of the compound butan-2-one.

The products of the chemical reaction between Na_(2)S_(2)O_(3),Cl and H_(2)O are :

RESONANCE ENGLISH-P BLOCK ELEMENTS-ALP PART 1 Comprehension # 1 SUBJECTIVE
  1. In P4 O10, the number of oxygen atoms bonded to each phosphorus atom i...

    Text Solution

    |

  2. Write the names of substances which have higher oxidation potential th...

    Text Solution

    |

  3. Why sulphur is able to show oxidation state of +4 and +6 with fluroine...

    Text Solution

    |

  4. Oxygen exists as a gas, while sulphur exists as a solid Why ?

    Text Solution

    |

  5. How is the presence of SO2 detected?

    Text Solution

    |

  6. Which aerosols deplete ozone?

    Text Solution

    |

  7. Oxygen almost invariably exhibits oxidation state of -2 but the other ...

    Text Solution

    |

  8. An aqueous solution of a gas (X) gives the following reactions : (a)...

    Text Solution

    |

  9. On heating rhombic sulphur it melts but viscosity of liquid increases ...

    Text Solution

    |

  10. {:(,underset(("Oxy acids of phosphoros"))("Column I"),,underset(("Char...

    Text Solution

    |

  11. {:("Column I","Column II"),((A)PbO(2)+HNO(3)to,(p)"One of the products...

    Text Solution

    |

  12. {:("Column I","Column II"),((A)2NO(2)overset("Cool")to,(p)"One of the ...

    Text Solution

    |

  13. P(4) reduces copper sulphate solution to metallic copper. True or Fa...

    Text Solution

    |

  14. Red phosphorus catches fire at room temperature. True or False

    Text Solution

    |

  15. If 200mL of 0.1M urea solution is mixed with 400mL of 0.2M glucose sol...

    Text Solution

    |

  16. N(2)O does not from hyponitrite with alkali. State True or False .

    Text Solution

    |

  17. In alkaline solution, with Devarda's alloy (Cu//Al//Zn) nitrites are r...

    Text Solution

    |

  18. N(2)O(5) is an acid anhydride of HNO(3). State True or False

    Text Solution

    |

  19. SO(3) does not turn starch iodate paper blue.

    Text Solution

    |

  20. Reduction of bisulphite solution and SO(2) with zin dust yields sulpha...

    Text Solution

    |