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What is the time required for 75 percent...

What is the time required for 75 percent completion of a first-order reaction?

A

`0.199 :1`

B

`0.420 :1`

C

`0.273:1`

D

`0.311:1`

Text Solution

Verified by Experts

The correct Answer is:
4

Time taken for `25%` completion.
`C_(1)C_(0)theta^(-k_(1)t)." "implies(3)/(4)=e^(-k_(1)t_(1))`
as `n(3//4)=-k_(1)b_(1)`so`t_(1)ln((4)/(3))`
time taken for `75%` completion `t_(2)=2.(ln2)/(k_(2))`
so required ration `(t_(1))/(t_(2))=(ln(4//3)k_(2))/(k_(1).2ln_(2))=(3)/(2)xx((ln4-ln3))/(ln4)=0.311:1`
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