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Match the complexed listed column -I wi...

Match the complexed listed column `-I` with type of hybridisation listed in column `-II` and select the correct answer using the code given below the lists `:`
`{:(,"Column"-I,,"Column"-II,),((a),[AuF_(4)]^(-),,(p)" "dsp^(2)"hybridisation",),((b),[Cu(CN)_(4)]^(3-),,(q)" "sp^(3)"hybridisation",),((c ),[Co(NH_(3))_(6)]^(3+),,(r)" "sp^(3)d^(2)"hybridisation",),((d),[Fe(H_(2)O)_(5)NO]^(2+),,(s)" "d^(2)sp^(3)"hybridisation",):}`

A

`{:(,"(a)","(b)","(c)","(d)"),(,p,q,s,r):}`

B

`{:(,"(a)","(b)","(c)","(d)"),(,p,s,q,r):}`

C

`{:(,"(a)","(b)","(c)","(d)"),(,q,p,r,s):}`

D

`{:(,"(a)","(b)","(c)","(d)"),(,s,q,p,r):}`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of matching the complexes in Column I with their corresponding hybridization types in Column II, we will analyze each complex individually and determine their hybridization based on the oxidation states and the nature of the ligands involved. ### Step-by-Step Solution: 1. **Identify the Complex: [AuF₄]⁻** - **Oxidation State of Au**: In this complex, the oxidation state of Au is +3. - **Electron Configuration**: The electron configuration of Au in +3 oxidation state is 5d⁸ (6s is empty). - **Hybridization**: Since Au has 8 electrons in the d-orbitals and can utilize the s and p orbitals for bonding, it undergoes **dsp² hybridization**. - **Match**: This corresponds to option (p). 2. **Identify the Complex: [Cu(CN)₄]³⁻** - **Oxidation State of Cu**: In this complex, the oxidation state of Cu is +1. - **Electron Configuration**: The electron configuration of Cu in +1 oxidation state is 3d¹⁰ (4s is empty). - **Hybridization**: With a completely filled d-orbital, Cu can only use its s and p orbitals for bonding, leading to **sp³ hybridization**. - **Match**: This corresponds to option (q). 3. **Identify the Complex: [Co(NH₃)₆]³⁺** - **Oxidation State of Co**: In this complex, the oxidation state of Co is +3. - **Electron Configuration**: The electron configuration of Co in +3 oxidation state is 3d⁵. - **Hybridization**: NH₃ is a strong field ligand, which causes pairing of electrons. Therefore, Co can use the paired d-orbitals along with s and p orbitals, leading to **d²sp³ hybridization**. - **Match**: This corresponds to option (s). 4. **Identify the Complex: [Fe(H₂O)₅NO]²⁺** - **Oxidation State of Fe**: In this complex, the oxidation state of Fe is +2. - **Electron Configuration**: The electron configuration of Fe in +2 oxidation state is 3d⁶. - **Hybridization**: H₂O is a weak field ligand, which does not cause pairing of electrons. Therefore, Fe uses its s and p orbitals along with the d-orbitals, leading to **sp³d² hybridization**. - **Match**: This corresponds to option (r). ### Summary of Matches: - (a) [AuF₄]⁻ → (p) dsp² hybridization - (b) [Cu(CN)₄]³⁻ → (q) sp³ hybridization - (c) [Co(NH₃)₆]³⁺ → (s) d²sp³ hybridization - (d) [Fe(H₂O)₅NO]²⁺ → (r) sp³d² hybridization ### Final Answer: The correct matching is: - a → p - b → q - c → s - d → r Thus, the answer code is **P Q S R**.

To solve the problem of matching the complexes in Column I with their corresponding hybridization types in Column II, we will analyze each complex individually and determine their hybridization based on the oxidation states and the nature of the ligands involved. ### Step-by-Step Solution: 1. **Identify the Complex: [AuF₄]⁻** - **Oxidation State of Au**: In this complex, the oxidation state of Au is +3. - **Electron Configuration**: The electron configuration of Au in +3 oxidation state is 5d⁸ (6s is empty). - **Hybridization**: Since Au has 8 electrons in the d-orbitals and can utilize the s and p orbitals for bonding, it undergoes **dsp² hybridization**. ...
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