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The colour of the coordination compounds...

The colour of the coordination compounds depends on the crystal field splitting . What will be the correct order of absorption of wavelength of light in the visible region, for the complexes, `[Co(NH_(3))_(6)]^(3+)`, `[Co(CN)_(6)]^(3-)` and `[Co(H_(2)O)_(6)]^(3+)`?

A

`IIIgtIgtIVgtII`

B

`IIgtIVgtIgtIII`

C

`IIIgtIgtIIgtIV`

D

`IgtIIIgtIVgtII`

Text Solution

Verified by Experts

The correct Answer is:
1

`Delta` corresponds to the wavelength of the visible light and `Delta =(hc)/(lambda)`
The order of ability to produce`d-` orbital splitting of various ligands ,
`COgtCN^(-)gtNO_(2)^(-)gtengtNH_(3)gtH_(2)OgtOH^(-)gtF^(-)gtCl^(-)gtBr^(-)gtI^(-)`
`{:("strong field","weak field"),("ligands","ligands"),("(larger "Delta")","(smaller"Delta")"):}`
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