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A dextro- rotatory optically active alky...

A dextro- rotatory optically active alkyl halide undergoes hydrolysis by `S_(N) 2` mechanism. The resulting alcohol is `:`

A

Dextorotatory

B

Laevorotatory

C

Optically inactive due to racemization

D

May be dexture or laevorotatory

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The correct Answer is:
To solve the question regarding the hydrolysis of a dextro-rotatory optically active alkyl halide undergoing an SN2 mechanism, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the SN2 Mechanism**: - The SN2 (Substitution Nucleophilic Bimolecular) mechanism involves a nucleophile attacking the electrophilic carbon atom from the opposite side of the leaving group. This results in an inversion of configuration at the carbon center. 2. **Identifying the Reactant**: - The reactant in this case is a dextro-rotatory alkyl halide. Dextrorotatory means that it rotates plane-polarized light to the right (clockwise). 3. **Nucleophilic Attack**: - In the SN2 mechanism, the nucleophile (in this case, hydroxide ion, OH-) attacks the carbon atom that is bonded to the halogen (the leaving group). This attack occurs from the back side of the carbon atom. 4. **Inversion of Configuration**: - Due to the back-side attack, the configuration of the carbon atom is inverted. If the original alkyl halide was dextrorotatory (D form), the product after the nucleophilic substitution will be levorotatory (L form) because of this inversion. 5. **Resulting Product**: - The product formed from the hydrolysis of the dextrorotatory alkyl halide through the SN2 mechanism will be an alcohol. Since the configuration has inverted, the resulting alcohol will be levorotatory. 6. **Conclusion**: - Therefore, the resulting alcohol from the hydrolysis of the dextro-rotatory optically active alkyl halide via the SN2 mechanism is levorotatory. ### Final Answer: The resulting alcohol is **levorotatory**.

To solve the question regarding the hydrolysis of a dextro-rotatory optically active alkyl halide undergoing an SN2 mechanism, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the SN2 Mechanism**: - The SN2 (Substitution Nucleophilic Bimolecular) mechanism involves a nucleophile attacking the electrophilic carbon atom from the opposite side of the leaving group. This results in an inversion of configuration at the carbon center. 2. **Identifying the Reactant**: ...
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Which of the following alkyl halides is hydrolysed by S_(N^(1)) mechanism?

Which of the following alkyl halides is hydrolysed by S_(N^(1)) mechanism?

Read the given passage and answer the questions number 1 to 5 that follow: The substitution reaction of alkyl halide mainly occurs by S_N 1 and S_N 2 mechanism. Whatever mechanism alkyl halides follow for the substitution reaction to occur, the polarity of the carbon halogen bond is responsible for these substitution reactions. The rate of S_N 1 reactions are governed by the stability of carbocation whereas for S_N 2 reactions steric factor is the deciding factor. If the starting material is a chiral compound, we may end up with an inverted product or racemic mixture depending upon the type of mechanism followed by alkyl halide. Cleavage of ethers with HI also governed by steric factor and stability of carbocation, which indicates that in organic chemistry, these two major factors help us in deciding the kind of product formed 1. Predict the stereochemistry of the product formed if an optically active alkyl halide undergoes substitution reaction by S_N 1 mechanism. 2. Name the instrument used for measuring the angle by which the plane polarised light is rotated. 3. Predict the major product formed when 2-Bromopentane reacts with alcoholic KOH. 4. Give one use of CHI_3 5. Write the structures of the products formed when anisole is treated with HI.

Which of the following halide undergoes in hydrolysis via S_(N^(1)) reaction?

SN^(2) reaction is a bimolecular reaction which takes places by the formation of T.S. Veolcity of the reaction depends on the concentration of the substrate as well as the nucleophile. The reaction is favoureed by strong Nu^(o-) and in the presence of polar aprotic sovlent, optically active halides give. Walden inversion by SN^(2) mechanism. The presence of hetro group (atom) at beta-C atom, unsaturation at beta-C and (-overset(O)overset(||)(C)-) group at alpha-C atomn favor SN^(2) mechanism. Allyl halides and benzyl halides give SN^(1) and SN^(2) reactions. Allyl halides alos give SN^(2) mechanism EDG at ortho- and para- postions in benzyl halides favors SN^(1) mechanism, wheras EWG favors SN^(2) mechanism. Which of the following will gives SN^(2) mechanism gt

2^(@) alkyl halides from alcohols via

SN^(2) reaction is a bimolecular reaction which takes places by the formation of T.S. Veolcity of the reaction depends on the concentration of the substrate as well as the nucleophile. The reaction is favoureed by strong Nu^(o-) and in the presence of polar aprotic sovlent, optically active halides give. Walken inversion by SN^(2) mechanism. The presence of hero group (atom) at beta-C atom, unsaturation at beta-C and (-overset(O)overset(||)(C)-) group at alpha-C atomn favor SN^(2) mechanism. Allyl halides and benzyl halides give SN^(1) and SN^(2) reactions. Allyl halides alos give SN^(2) mechanism EDG at ortho- and para- postions in benzyl halides favors SN^(1) mechanism, wheras EWG favors SN^(2) mechanism. Which of the following will give SN^(2) mechanism?

SN^(2) reaction is a bimolecular reaction which takes places by the formation of T.S. Veolcity of the reaction depends on the concentration of the substrate as well as the nucleophile. The reaction is favoureed by strong Nu^(o-) and in the presence of polar aprotic sovlent, optically active halides give. Walken inversion by SN^(2) mechanism. The presence of hero group (atom) at beta-C atom, unsaturation at beta-C and (-overset(O)overset(||)(C)-) group at alpha-C atomn favor SN^(2) mechanism. Allyl halides and benzyl halides give SN^(1) and SN^(2) reactions. Allyl halides alos give SN^(2) mechanism EDG at ortho- and para- postions in benzyl halides favors SN^(1) mechanism, wheras EWG favors SN^(2) mechanism. Which of the following will give Walden inversion ?

SN^(2) reaction is a bimolecular reaction which takes places by the formation of T.S. Veolcity of the reaction depends on the concentration of the substrate as well as the nucleophile. The reaction is favoureed by strong Nu^(o-) and in the presence of polar aprotic sovlent, optically active halides give. Walken inversion by SN^(2) mechanism. The presence of hero group (atom) at beta-C atom, unsaturation at beta-C and (-overset(O)overset(||)(C)-) group at alpha-C atomn favor SN^(2) mechanism. Allyl halides and benzyl halides give SN^(1) and SN^(2) reactions. Allyl halides alos give SN^(2) mechanism EDG at ortho- and para- postions in benzyl halides favors SN^(1) mechanism, wheras EWG favors SN^(2) mechanism. Which of the following will give SN^(1) reaction?

Which of the following alkyl halides undergoes the fastest S_(N^(1)) reaction ?

RESONANCE ENGLISH-ALKYL HALIDE, ALCOHOL, PHENOL, ETHER-ORGANIC CHEMISTRY(Alkyl Halide, Alcohol,Phenol,Ether)
  1. Draw structure for n-pentyl bromide

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  2. A dextro- rotatory optically active alkyl halide undergoes hydrolysis ...

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  3. The reaction, is an example of ,

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  4. Neopentyl bromide undergoes dehydro halogenation to give alkene even t...

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  5. From Williamson's synthesis preparation of which of the following is p...

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  6. Ethyl alcohol is heated with conc. H(2)SO(4) at 170^(@)C. The product ...

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  7. CH(2)=CH(2)overset(HBr)rarrXoverset(Ag.KOH)rarrYunderset(I(2))overset(...

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  8. Methyl alcohol when reacted with carbon monoxide using cobalt or rhodi...

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  9. Which of the following is added to chloroform to slow down its aerial ...

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  10. The catalyst used in the preparation of an alkyl chloride by the actio...

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  11. Which of the following does not give a precipitate with alcoholic AgNO...

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  12. What do you mean by nucleophile ?

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  13. 1-Phenyl ethanol can be prepared by the reaction of C(6)H(5)CHO with :

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  14. When alkyl halide is heated with dry Ag(2)O. It produces :

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  15. When ethyl alcohol is oxidised with PCC, it gives :

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  16. p-Nitrophenol and o-nitrophenol can be separated by

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  17. Phosgene is a poisonous gas obtained in chloroform bottles, substance ...

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  18. Order of hydrolysis of the following in increasing order is : under...

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  19. CHCl(3)+OH^(-)rarrHCOO^(-), intermediate of this reaction can be

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  20. Ethers can not be prepared by :

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