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The end product of the reaction, Ethyl...

The end product of the reaction,
Ethyl amine `overset(HNO_(2))rarr(A)overset(PCl_(5))rarr(B)overset(KCN)rarr(C )` `(C)` is,

A

Propanenitrile

B

Trethylamine

C

diethylamine

D

propylamine

Text Solution

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The correct Answer is:
To determine the end product (C) of the given reaction sequence involving ethyl amine, we will break down each step of the reaction as follows: ### Step 1: Reaction of Ethyl Amine with HNO2 - **Reaction**: Ethyl amine (C2H5NH2) reacts with nitrous acid (HNO2). - **Product (A)**: This reaction forms an unstable diazonium salt. The diazonium salt formed is C2H5N2^+ (ethyl diazonium ion), which can be represented as C2H5-N≡N^+. - **Mechanism**: The nitrogen in HNO2 reacts with the ethyl amine to form the diazonium salt. The reaction can be summarized as: \[ C2H5NH2 + HNO2 \rightarrow C2H5N2^+ + H2O \] ### Step 2: Reaction of Diazonium Salt with PCl5 - **Reaction**: The diazonium salt (A) reacts with phosphorus pentachloride (PCl5). - **Product (B)**: The diazonium ion undergoes a substitution reaction to form ethyl chloride (C2H5Cl). - **Mechanism**: The diazonium salt loses nitrogen gas (N2) and forms a carbocation, which then reacts with Cl^- from PCl5: \[ C2H5N2^+ + PCl5 \rightarrow C2H5Cl + N2 + POCl3 \] ### Step 3: Reaction of Ethyl Chloride with KCN - **Reaction**: Ethyl chloride (B) reacts with potassium cyanide (KCN). - **Product (C)**: This reaction leads to the formation of propionitrile (C2H5C≡N), which is also known as ethyl cyanide. - **Mechanism**: The reaction proceeds via an SN2 mechanism, where the cyanide ion (CN^-) attacks the electrophilic carbon in ethyl chloride: \[ C2H5Cl + KCN \rightarrow C2H5C≡N + KCl \] ### Final Product Thus, the final product (C) of the entire reaction sequence is **propionitrile (C2H5C≡N)**. ### Summary of Products - A: Ethyl diazonium ion (C2H5N2^+) - B: Ethyl chloride (C2H5Cl) - C: Propionitrile (C2H5C≡N)
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RESONANCE ENGLISH-NITROGEN CONTAINING COMPOUNDS-ORGANIC CHEMISTRY(Nitrogen containing Compounds)
  1. Which of the following compound gives secondary amine on reduction.

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  2. Hinsber's reagent is used to distinguish between

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  3. The end product of the reaction, Ethyl amine overset(HNO(2))rarr(A)o...

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  4. In which of the following reaction migration of alkyl group from ''C''...

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  5. The R in the given reaction sequence is -

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  6. The uncertainties in position and the velocity of a particle are 10^(-...

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  7. The Cimetidine has serveral nitrogen atom in its structure. Identify t...

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  8. The product of given reaction is

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  9. Which of the following is capable of forming a zwitter ion ?

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  10. The uncertainties in position and the velocity of a particle are 10^(-...

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  11. In the diazotisation of anline with sodium nitrite and hydrochloride a...

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  12. Starting from propanoic acid, the following reaction were carried acid...

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  13. In the reaction, C(6)H(5)NH(2)underset(0-5^(@)C)overset(NaNO(2)+HCl)...

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  14. In the given reaction product P is :

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  15. P ( major product ), P is

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  16. Identify A,C(6)H(11)N, for which the given information is availabel . ...

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  17. An optically inactive amine (A) is methylated with excess of CH(3)I an...

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  18. The product P formed in the given reaction sequence is .

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  19. Identify the correct statement.

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  20. Which statement is incorrect.

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