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Starting from propanoic acid, the follow...

Starting from propanoic acid, the following reaction were carried acid `overset(SOCl_2)toXoverset(NH_3)toYoverset(Br_2+KOH)toZ` What is the compound?

A

`CH_(3)-CH_(2)-Br`

B

`CH_(3)-CH_(2)-NH_(2)`

C

D

`CH_(3)-CH_(2)-CH_(2)-NH_(2)`

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The correct Answer is:
To solve the problem step-by-step, we will analyze each reaction starting from propanoic acid. ### Step 1: Reaction of Propanoic Acid with Thionyl Chloride (SOCl₂) 1. **Starting Material**: Propanoic acid (CH₃CH₂COOH). 2. **Reaction**: When propanoic acid reacts with thionyl chloride (SOCl₂), it undergoes a conversion to form an acyl chloride. 3. **Product Formation**: The hydroxyl (-OH) group of propanoic acid is replaced by a chlorine atom, resulting in the formation of propanoyl chloride (CH₃CH₂COCl). **Chemical Equation**: \[ \text{CH}_3\text{CH}_2\text{COOH} + \text{SOCl}_2 \rightarrow \text{CH}_3\text{CH}_2\text{COCl} + \text{SO}_2 + \text{HCl} \] ### Step 2: Reaction of Propanoyl Chloride with Ammonia (NH₃) 1. **Starting Material**: Propanoyl chloride (CH₃CH₂COCl). 2. **Reaction**: When propanoyl chloride reacts with ammonia (NH₃), the chlorine atom is replaced by an amine group (-NH₂). 3. **Product Formation**: This results in the formation of propanamide (CH₃CH₂CONH₂). **Chemical Equation**: \[ \text{CH}_3\text{CH}_2\text{COCl} + \text{NH}_3 \rightarrow \text{CH}_3\text{CH}_2\text{CONH}_2 + \text{HCl} \] ### Step 3: Reaction of Propanamide with Bromine and KOH (Hofmann Reaction) 1. **Starting Material**: Propanamide (CH₃CH₂CONH₂). 2. **Reaction**: When propanamide is treated with bromine (Br₂) in the presence of potassium hydroxide (KOH), it undergoes the Hofmann degradation reaction. 3. **Product Formation**: This reaction results in the removal of the carbonyl group (C=O) and the formation of an amine. The final product is ethylamine (CH₃CH₂NH₂). **Chemical Equation**: \[ \text{CH}_3\text{CH}_2\text{CONH}_2 + \text{Br}_2 + \text{KOH} \rightarrow \text{CH}_3\text{CH}_2\text{NH}_2 + \text{KBr} + \text{H}_2\text{O} \] ### Final Product The final compound Z obtained from the series of reactions starting from propanoic acid is **ethylamine (CH₃CH₂NH₂)**. ---

To solve the problem step-by-step, we will analyze each reaction starting from propanoic acid. ### Step 1: Reaction of Propanoic Acid with Thionyl Chloride (SOCl₂) 1. **Starting Material**: Propanoic acid (CH₃CH₂COOH). 2. **Reaction**: When propanoic acid reacts with thionyl chloride (SOCl₂), it undergoes a conversion to form an acyl chloride. 3. **Product Formation**: The hydroxyl (-OH) group of propanoic acid is replaced by a chlorine atom, resulting in the formation of propanoyl chloride (CH₃CH₂COCl). ...
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RESONANCE ENGLISH-NITROGEN CONTAINING COMPOUNDS-ORGANIC CHEMISTRY(Nitrogen containing Compounds)
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  2. In the diazotisation of anline with sodium nitrite and hydrochloride a...

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  3. Starting from propanoic acid, the following reaction were carried acid...

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  4. In the reaction, C(6)H(5)NH(2)underset(0-5^(@)C)overset(NaNO(2)+HCl)...

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  5. In the given reaction product P is :

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  6. P ( major product ), P is

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  7. Identify A,C(6)H(11)N, for which the given information is availabel . ...

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  8. An optically inactive amine (A) is methylated with excess of CH(3)I an...

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  9. The product P formed in the given reaction sequence is .

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  10. Identify the correct statement.

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  11. Which statement is incorrect.

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  12. What will be the major product when 2-Aminopropane is treated with nit...

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  13. Which of the following product (s) will be obtained when isopropylamin...

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  14. Which of the following compounds will give N(2)(g) on treatment with H...

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  15. Compound (x)(m.f=C(7)H(8)N), on reaction with NaNO(2) and conc. HCl at...

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  16. Pyridine is less basic than triethylamine because

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  17. The reagents are

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  18. Arrange following Amines for rate of reaction with CHCl(3)+KOH ?

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  19. Which of the following is correct order of basic strength for the give...

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  20. Which nitrogen atom is most basic ?

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