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An optically inactive amine (A) is methy...

An optically inactive amine `(A)` is methylated with excess of `CH_(3)I` and there after reacted with `AgOH` to form alkene `(B)`. The alkene B after ozonolysis gives `HCHO` and `CH_(3)CH_(2)CH_(2)CHO`. A and B in the reaction are respectively.

A

`CH_(3)-CH_(2)-CH_(2)-NH_(2)" "&" "CH_(3)-CH_(2)-CH=CH_(2)`

B

`CH_(3)-CH_(2)-underset(underset(NH_(2))|)(C)H-CH_(2)-CH_(2)" "&" "CH_(3)-CH_(2)-CH=CH-CH_(3)`

C

`CH_(3)-CH_(2)-CH_(2)-CH_(2)-NH_(2)" "&" "CH_(3)-CH_(2)-CH_(2)-CH=CH_(2)`

D

`CH_(3)-CH_(2)-CH_(2)-underset(underset(NH_(2))|)(C)H-CH_(3)" "&" "CH_(3)-CH_(2)-CH_(2)-CH=CH_(2)`

Text Solution

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The correct Answer is:
To solve the problem, we need to identify the compounds A and B based on the information provided. Here’s a step-by-step breakdown of the solution: ### Step 1: Understanding the Reaction The problem states that an optically inactive amine (A) is methylated with excess of CH₃I. Methylation typically involves the addition of a methyl group to the amine, which can lead to the formation of a quaternary ammonium salt. ### Step 2: Identifying Alkene (B) After methylation, the compound is reacted with AgOH, which suggests a dehydrohalogenation reaction that leads to the formation of an alkene (B). The ozonolysis of alkene (B) gives formaldehyde (HCHO) and butanal (CH₃CH₂CH₂CHO). ### Step 3: Analyzing the Ozonolysis Products The ozonolysis products are HCHO and CH₃CH₂CH₂CHO. The presence of these products indicates that the original alkene (B) must have a structure that, when cleaved, results in these aldehydes. ### Step 4: Constructing Alkene (B) The ozonolysis suggests that alkene (B) is likely 1-pentene (CH₂=CH-CH₂-CH₂-CH₃). This structure, when ozonolyzed, would yield: - HCHO from the terminal carbon (C1) - CH₃CH₂CH₂CHO from the other end (C5) ### Step 5: Identifying Amine (A) Since we know that amine (A) is optically inactive, it cannot have a chiral center. The simplest amine that can lead to 1-pentene upon methylation and subsequent reaction with AgOH is butylamine (C₄H₉NH₂). ### Conclusion Thus, the compounds are: - **Compound A (Optically inactive amine)**: Butylamine (C₄H₉NH₂) - **Compound B (Alkene)**: 1-Pentene (C₅H₁₀) ### Final Answer A and B in the reaction are respectively: - A: Butylamine - B: 1-Pentene

To solve the problem, we need to identify the compounds A and B based on the information provided. Here’s a step-by-step breakdown of the solution: ### Step 1: Understanding the Reaction The problem states that an optically inactive amine (A) is methylated with excess of CH₃I. Methylation typically involves the addition of a methyl group to the amine, which can lead to the formation of a quaternary ammonium salt. ### Step 2: Identifying Alkene (B) After methylation, the compound is reacted with AgOH, which suggests a dehydrohalogenation reaction that leads to the formation of an alkene (B). The ozonolysis of alkene (B) gives formaldehyde (HCHO) and butanal (CH₃CH₂CH₂CHO). ...
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