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What will be the major product when 2-Am...

What will be the major product when `2-`Aminopropane is treated with nitrous acid ?

A

`1-` Propanol

B

`2-` Propanol

C

Propene

D

Cyclopropane

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The correct Answer is:
To determine the major product when 2-aminopropane is treated with nitrous acid, we can follow these steps: ### Step 1: Identify the Structure of 2-Aminopropane 2-aminopropane has the following structure: - It is an amine with the formula CH3-CH(NH2)-CH3. - This means there is an amino group (NH2) attached to the second carbon of a three-carbon chain. ### Step 2: Reaction with Nitrous Acid When 2-aminopropane is treated with nitrous acid (HNO2), a diazonium salt is formed. The reaction can be represented as follows: - The amino group (NH2) reacts with nitrous acid to form a diazonium salt (R-N2^+), where R is the rest of the molecule. ### Step 3: Formation of Diazonium Salt The diazonium salt formed from 2-aminopropane is: - CH3-CH(N2^+)-CH3 + Cl^- - Here, the nitrogen from the amino group is replaced by a diazonium group (N2^+). ### Step 4: Decomposition of Diazonium Salt Diazonium salts are generally unstable, especially when there is no resonance stabilization. Therefore, the diazonium salt will decompose: - The diazonium salt loses nitrogen gas (N2) and forms a carbocation (R^+). ### Step 5: Formation of the Final Product The carbocation formed is stabilized by the presence of water (H2O), which provides hydroxide ions (OH^-): - The carbocation will react with water to form an alcohol. - The final product is 2-propanol (CH3-CHOH-CH3). ### Conclusion The major product when 2-aminopropane is treated with nitrous acid is 2-propanol. ### Final Answer: The major product is 2-propanol. ---

To determine the major product when 2-aminopropane is treated with nitrous acid, we can follow these steps: ### Step 1: Identify the Structure of 2-Aminopropane 2-aminopropane has the following structure: - It is an amine with the formula CH3-CH(NH2)-CH3. - This means there is an amino group (NH2) attached to the second carbon of a three-carbon chain. ### Step 2: Reaction with Nitrous Acid ...
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