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Given at 350Kp(A)^@=300 "torr" and p(B)^...

Given at `350Kp_(A)^@=300 "torr"` and `p_(B)^@=800 "torr"` the composition
of the mixture having a normal boiling point of `350K` is

A

`X_(A)=0.08`

B

`X_(A)=0.06`

C

`X_(A)=0.04`

D

`X_(A)=0.02`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we will use Raoult's Law, which states that the total pressure of a mixture of volatile components is equal to the sum of the partial pressures of each component. The partial pressure of each component can be calculated using the formula: \[ P_T = P_{A}^0 \cdot X_A + P_{B}^0 \cdot X_B \] Where: - \( P_T \) = total pressure of the mixture - \( P_{A}^0 \) = vapor pressure of component A - \( P_{B}^0 \) = vapor pressure of component B - \( X_A \) = mole fraction of component A - \( X_B \) = mole fraction of component B Given: - \( P_T = 760 \, \text{torr} \) - \( P_{A}^0 = 300 \, \text{torr} \) - \( P_{B}^0 = 800 \, \text{torr} \) ### Step-by-step Solution: 1. **Set up the equation using Raoult's Law:** \[ P_T = P_{A}^0 \cdot X_A + P_{B}^0 \cdot X_B \] Since \( X_A + X_B = 1 \), we can express \( X_B \) as \( 1 - X_A \). 2. **Substitute \( X_B \) in the equation:** \[ 760 = 300 \cdot X_A + 800 \cdot (1 - X_A) \] 3. **Expand the equation:** \[ 760 = 300 \cdot X_A + 800 - 800 \cdot X_A \] \[ 760 = 800 - 500 \cdot X_A \] 4. **Rearrange the equation to isolate \( X_A \):** \[ 500 \cdot X_A = 800 - 760 \] \[ 500 \cdot X_A = 40 \] 5. **Solve for \( X_A \):** \[ X_A = \frac{40}{500} = 0.08 \] 6. **Find \( X_B \):** \[ X_B = 1 - X_A = 1 - 0.08 = 0.92 \] ### Final Answer: The composition of the mixture at the normal boiling point of 350 K is: - \( X_A = 0.08 \) - \( X_B = 0.92 \)

To solve the problem, we will use Raoult's Law, which states that the total pressure of a mixture of volatile components is equal to the sum of the partial pressures of each component. The partial pressure of each component can be calculated using the formula: \[ P_T = P_{A}^0 \cdot X_A + P_{B}^0 \cdot X_B \] Where: - \( P_T \) = total pressure of the mixture - \( P_{A}^0 \) = vapor pressure of component A - \( P_{B}^0 \) = vapor pressure of component B ...
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