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X(C(4)H(9)Br) underset(Delta) overset(al...

`X(C_(4)H_(9)Br) underset(Delta) overset(alc.KOH)to Yoverset(Br_(2)//"CC"l_(4)) rarrZ underset(Delta) overset(NaNH_(2)(2eq.))to W underset(("Tollen's reagent")) overset(AgNO_(3)+NH_(4)OH)to`white ppt
Reductive ozonolysis of `Y` yields

A

`CH_(3)CH_(2)CHO` and `HCHO`

B

`2` moles of `CH_(3)CHO`

C

`CH_(3)CO CH_(3)` and `HCHO`

D

`CH_(3)CH_(2)COOH` and `HCOOH`

Text Solution

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The correct Answer is:
To solve the given question step by step, we will analyze each part of the reaction sequence provided. ### Step 1: Identify Compound X The compound X is given as C₄H₉Br. This indicates that it is a brominated alkane. The presence of bromine suggests that it can undergo elimination reactions. ### Step 2: Reaction of X with Alcoholic KOH When X reacts with alcoholic KOH under heat, it will undergo an elimination reaction (dehydrohalogenation) to form an alkene (Y). The structure of Y can be predicted as follows: - Since X has 4 carbons and one bromine, we can assume a linear structure. - The elimination will likely produce a double bond. Assuming the structure of X is 1-bromobutane (CH₃CH₂CH₂CH₂Br), the elimination reaction will yield: - **Y = But-1-ene (CH₃CH₂CH=CH₂)** ### Step 3: Reaction of Y with Br₂ in CCl₄ Next, Y (But-1-ene) reacts with Br₂ in CCl₄. This reaction will add bromine across the double bond, resulting in a dibrominated compound (Z): - **Z = 1,2-Dibromobutane (CH₃CHBrCHBrCH₃)** ### Step 4: Reaction of Z with NaNH₂ Z then reacts with 2 equivalents of NaNH₂, which will facilitate a double elimination reaction to form an alkyne (W): - The elimination will remove the two bromine atoms and two hydrogen atoms, resulting in: - **W = Butyne (CH₃C≡CCH₃)** ### Step 5: Reaction of W with Tollen's Reagent W (Butyne) reacts with Tollen's reagent (AgNO₃ + NH₄OH). Tollen's reagent is used to test for aldehydes, and since butyne can be oxidized to form an aldehyde, we can expect: - **White precipitate of silver (Ag) indicates the presence of an aldehyde.** ### Step 6: Reductive Ozonolysis of Y Finally, we need to determine the products of the reductive ozonolysis of Y (But-1-ene). The ozonolysis of alkenes typically results in the formation of carbonyl compounds (aldehydes or ketones). For But-1-ene: - The ozonolysis will cleave the double bond and add oxygen, resulting in: - **Products: CH₃CH₂CHO (butanal) and HCHO (formaldehyde)** ### Summary of Structures - **X = 1-bromobutane (CH₃CH₂CH₂CH₂Br)** - **Y = But-1-ene (CH₃CH₂CH=CH₂)** - **Z = 1,2-Dibromobutane (CH₃CHBrCHBrCH₃)** - **W = Butyne (CH₃C≡CCH₃)** - **Reductive ozonolysis of Y yields: Butanal (CH₃CH₂CHO) and Formaldehyde (HCHO)**

To solve the given question step by step, we will analyze each part of the reaction sequence provided. ### Step 1: Identify Compound X The compound X is given as C₄H₉Br. This indicates that it is a brominated alkane. The presence of bromine suggests that it can undergo elimination reactions. ### Step 2: Reaction of X with Alcoholic KOH When X reacts with alcoholic KOH under heat, it will undergo an elimination reaction (dehydrohalogenation) to form an alkene (Y). The structure of Y can be predicted as follows: - Since X has 4 carbons and one bromine, we can assume a linear structure. ...
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