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The maximum pH of a solution which is ha...

The maximum `pH` of a solution which is having `0.10M` in `Mg^(2+)` and from which `Mg(OH)_(2)` is not precipated is: (Given `K_(sp)Mg(OH)_(2)=4xx10^(-11)M^(3)){log2=0.30}`

A

`10.3`

B

`3.7`

C

`7.5`

D

`9.3`

Text Solution

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The correct Answer is:
To find the maximum pH of a solution with a concentration of \(0.10 \, M\) in \(Mg^{2+}\) from which \(Mg(OH)_2\) does not precipitate, we follow these steps: ### Step 1: Understand the condition for precipitation For \(Mg(OH)_2\) to not precipitate, the ionic product of the ions must be less than the solubility product (\(K_{sp}\)). The dissociation of \(Mg(OH)_2\) can be represented as: \[ Mg(OH)_2 \rightleftharpoons Mg^{2+} + 2OH^{-} \] The ionic product (\(IP\)) is given by: \[ IP = [Mg^{2+}][OH^{-}]^2 \] We need to ensure that: \[ IP < K_{sp} \] ### Step 2: Substitute the known values Given: - \(K_{sp} = 4 \times 10^{-11} \, M^3\) - \([Mg^{2+}] = 0.10 \, M\) Substituting into the inequality: \[ [Mg^{2+}][OH^{-}]^2 < 4 \times 10^{-11} \] This becomes: \[ 0.10 \times [OH^{-}]^2 < 4 \times 10^{-11} \] ### Step 3: Solve for \([OH^{-}]\) Rearranging the inequality gives: \[ [OH^{-}]^2 < \frac{4 \times 10^{-11}}{0.10} \] Calculating the right side: \[ [OH^{-}]^2 < 4 \times 10^{-10} \] Taking the square root: \[ [OH^{-}] < 2 \times 10^{-5} \, M \] ### Step 4: Calculate the maximum pOH The maximum pOH can be calculated using: \[ pOH = -\log[OH^{-}] \] Substituting the maximum concentration of hydroxide ions: \[ pOH = -\log(2 \times 10^{-5}) \] Using the logarithmic properties: \[ pOH = -\log(2) - \log(10^{-5}) = -\log(2) + 5 \] Given that \(\log(2) \approx 0.30\): \[ pOH = 5 - 0.30 = 4.70 \] ### Step 5: Calculate the maximum pH Using the relationship between pH and pOH: \[ pH + pOH = 14 \] Thus, \[ pH = 14 - pOH = 14 - 4.70 = 9.30 \] ### Final Answer The maximum pH of the solution, from which \(Mg(OH)_2\) is not precipitated, is: \[ \boxed{9.30} \]

To find the maximum pH of a solution with a concentration of \(0.10 \, M\) in \(Mg^{2+}\) from which \(Mg(OH)_2\) does not precipitate, we follow these steps: ### Step 1: Understand the condition for precipitation For \(Mg(OH)_2\) to not precipitate, the ionic product of the ions must be less than the solubility product (\(K_{sp}\)). The dissociation of \(Mg(OH)_2\) can be represented as: \[ Mg(OH)_2 \rightleftharpoons Mg^{2+} + 2OH^{-} \] The ionic product (\(IP\)) is given by: ...
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