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With t taken in seconds and I taken in a...

With t taken in seconds and I taken in amp, the variation of I follows the equation `t^(2) + I^(2) = 25`
What amount of Ag will be electrodeposited with this current flowing in the interval 0-5 second? (Ag=108)

A

22 mg

B

66 mg

C

77 mg

D

88 mg

Text Solution

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The correct Answer is:
To solve the problem of how much silver (Ag) will be electrodeposited when the current varies according to the equation \( t^2 + I^2 = 25 \) over the interval from 0 to 5 seconds, we will follow these steps: ### Step 1: Understand the relationship between current (I) and time (t) Given the equation: \[ t^2 + I^2 = 25 \] We can express the current \( I \) in terms of time \( t \): \[ I = \sqrt{25 - t^2} \] ### Step 2: Determine the charge (Q) over the time interval The charge \( Q \) can be calculated using the formula: \[ Q = \int_0^T I \, dt \] where \( T = 5 \) seconds. Substituting \( I \) from Step 1: \[ Q = \int_0^5 \sqrt{25 - t^2} \, dt \] ### Step 3: Evaluate the integral The integral \( \int \sqrt{25 - t^2} \, dt \) represents the area of a quarter circle with radius 5. The area of a quarter circle is given by: \[ \text{Area} = \frac{1}{4} \pi r^2 = \frac{1}{4} \pi (5^2) = \frac{25\pi}{4} \] Thus, the charge \( Q \) over the interval from 0 to 5 seconds is: \[ Q = \frac{25\pi}{4} \] ### Step 4: Calculate the weight of silver deposited Using Faraday's law of electrolysis, the weight \( W \) of the substance deposited is given by: \[ W = \frac{Q \cdot M}{F} \] where: - \( M \) is the molar mass of silver (Ag), which is 108 g/mol, - \( F \) is Faraday's constant, approximately \( 96500 \, C/mol \). Substituting \( Q \): \[ W = \frac{\left(\frac{25\pi}{4}\right) \cdot 108}{96500} \] ### Step 5: Calculate the numerical value Calculating \( W \): 1. Calculate \( \frac{25\pi}{4} \): \[ \frac{25\pi}{4} \approx \frac{25 \times 3.14}{4} \approx 19.63 \, C \] 2. Substitute into the weight equation: \[ W = \frac{19.63 \cdot 108}{96500} \approx \frac{2128.04}{96500} \approx 0.022 \, g \] 3. Convert grams to milligrams: \[ 0.022 \, g = 22 \, mg \] ### Final Answer The amount of silver (Ag) electrodeposited is **22 mg**.

To solve the problem of how much silver (Ag) will be electrodeposited when the current varies according to the equation \( t^2 + I^2 = 25 \) over the interval from 0 to 5 seconds, we will follow these steps: ### Step 1: Understand the relationship between current (I) and time (t) Given the equation: \[ t^2 + I^2 = 25 \] We can express the current \( I \) in terms of time \( t \): ...
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