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Dissolution of a non-volatile solute int...

Dissolution of a non-volatile solute into a liquid leads to the-

A

decrease of entropy

B

increase in tendency of the liquid to freeze

C

increases in tendency to pass into the vapour phase

D

decrease in tendency of the liquid to freeze

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The correct Answer is:
To solve the question regarding the dissolution of a non-volatile solute into a liquid, we will analyze the effects of this process step by step. ### Step-by-Step Solution: 1. **Understanding the Concept of Non-volatile Solute**: - A non-volatile solute is a substance that does not vaporize easily and has a negligible vapor pressure compared to the solvent. When it is dissolved in a liquid, it affects the physical properties of the solvent. **Hint**: Remember that non-volatile solutes do not contribute to the vapor pressure of the solution. 2. **Effect on Entropy**: - When a non-volatile solute is dissolved in a solvent, the randomness or disorder of the system increases. This is because the solute particles disrupt the orderly arrangement of solvent molecules, leading to an increase in entropy (ΔS > 0). **Hint**: Think about how mixing substances generally increases disorder in a system. 3. **Freezing Point Depression**: - The addition of a non-volatile solute lowers the freezing point of the solvent. This phenomenon is known as freezing point depression. The presence of solute particles interferes with the formation of the solid phase (ice), thus requiring a lower temperature to freeze. **Hint**: Recall that adding solute to a solvent typically lowers the temperature at which the solvent freezes. 4. **Vapor Pressure and Boiling Point Elevation**: - The presence of a non-volatile solute decreases the vapor pressure of the solvent. Consequently, this results in an elevation of the boiling point of the solution. This is known as boiling point elevation. The solution must be heated to a higher temperature to reach the vapor pressure necessary for boiling. **Hint**: Consider how solute particles affect the ability of solvent molecules to escape into the vapor phase. 5. **Conclusion**: - Based on the above analysis, we can conclude that the dissolution of a non-volatile solute into a liquid leads to: - An increase in entropy (ΔS > 0). - A decrease in the tendency of the liquid to freeze (freezing point depression). - An increase in the boiling point (boiling point elevation). Therefore, the correct answer to the question is that it **increases the tendency of the liquid to freeze** (which is actually a decrease in the freezing point). ### Final Answer: The dissolution of a non-volatile solute into a liquid leads to a **decrease in the tendency of the liquid to freeze**.

To solve the question regarding the dissolution of a non-volatile solute into a liquid, we will analyze the effects of this process step by step. ### Step-by-Step Solution: 1. **Understanding the Concept of Non-volatile Solute**: - A non-volatile solute is a substance that does not vaporize easily and has a negligible vapor pressure compared to the solvent. When it is dissolved in a liquid, it affects the physical properties of the solvent. **Hint**: Remember that non-volatile solutes do not contribute to the vapor pressure of the solution. ...
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A system of greater disorder of molecules is more probable. The disorder of molecules is reflected by the entropy of the system. A liquid vapourizes to form a more disordered gas. When a solute is present, there is additional contribution to the entropy of the liquid due to increased randomness. As the entropy of solution is higher than that of pure liquid, there is weaker tendency to form the gas. Thus, a solute (non-volatile) lowers the vapour pressure of a liquid, and hence a higher boiling point of the solution. Similarly, the greater randomness of the solution opposes the tendercy to freeze. In consequence, a lower temperature must be reached for achieving the equilibrium between the solid (frozen solvent) and the solution. The elevation in boiling point (DeltaT_(b)) and depression in freezing point (DeltaT_(f)) of a solution are the colligative properties which depend only on the concentration of particles of the solute and not their identity. For dilute solutions, (DeltaT_(b)) and (DeltaT_(f)) are proportional to the molarity of the solute in the solution. Dissolution of a non-volatile solute into a liquid leads to

For a non-volatile solute

How can you justify the observation that the V.P. of solution of a non-volatile solute in a given solvent is less than that of pure solvent. Also state the law concerning the observation.

A solution of urea contains 8.6 g per litre. It is isotonic with 5% solution of a non-volatile solute. The molecular mass of the solute will be :

Lowering of vapour pressure of 1.00 m solution of a non-volatile solute in a hypothetical solvent of molar mass 40 g/mole at its normal boiling point is:

At equilibrium, the rate of dissolution of a solid solute in a volatile liquid solvent is

The vapour pressure (VP) of a dilute solution of non-volatile solute is P and the VP of a pure solvent is P^(@) . The lowering of the VP is

The boiling point of a solution gets raised on dissolution of non-volatile solute. Explain how this property is used for finding the molecular mass of the solute ?

The mole fraction of the solvent in the solution of a non-volatile solute is 0.980. The relative lowering of vapour pressure is :

If P^(@) the vapour pressure of a pure solvent and P is the vapour pressure of the solution prepared by dissolving a non volatile solute in it. The mole fraction of the solvent X_(A) is given by:

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