`{:("Column-I","Column-II"),((A)"Acetone +"CHCl_3, (p)DeltaS_("mix") gt0),((B)"Ethanol + Water ",(q)DeltaV_(mix)gt0),((C )C_2H_5Br+C_2H_5I,(r)DeltaH_(mix) lt 0),((D)"Aceton + Benzene",(s)"Maximum boiling azeotropes"),(,(t)"Minimum boiling azeotropes"):}`

Explanation

To solve the question, we need to match the compounds in Column-I with the corresponding conditions in Column-II based on their behavior in solutions, particularly in relation to Raoult's law and the concepts of mixing enthalpy (ΔH), mixing volume (ΔV), and mixing entropy (ΔS).

### Step-by-Step Solution:

1. **Identify the behavior of each mixture:**
- **(A) Acetone + CHCl₃:** This mixture is known to show a negative deviation from Raoult's law. Therefore, it will have ΔS(mix) > 0 and ΔH(mix) < 0. This means it can be matched with (r) ΔH(mix) < 0.
- **(B) Ethanol + Water:** This mixture shows a positive deviation from Raoult's law, which means it has ΔV(mix) > 0. It is also known for forming minimum boiling azeotropes, so it matches with (t) ΔV(mix) > 0.
- **(C) C₂H₅Br + C₂H₅I:** These compounds are ideal solutions and do not show significant deviations from Raoult's law. Thus, they will have ΔS(mix) > 0, which leads to matching with (p) ΔS(mix) > 0.
- **(D) Acetone + Benzene:** This mixture shows a positive deviation from Raoult's law, indicating ΔV(mix) > 0 and is associated with minimum boiling azeotropes. Therefore, it matches with (t) ΔV(mix) > 0.

2. **Match the results:**
- (A) Acetone + CHCl₃ → (r) ΔH(mix) < 0
- (B) Ethanol + Water → (t) ΔV(mix) > 0
- (C) C₂H₅Br + C₂H₅I → (p) ΔS(mix) > 0
- (D) Acetone + Benzene → (s) Maximum boiling azeotropes

### Final Matches:
- A → r
- B → t
- C → p
- D → s